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प्रश्न
The probability density plots of 1s and 2s orbitals are given in Figure:
The density of dots in a region represents the probability density of finding electrons in the region.
On the basis of above diagram which of the following statements is incorrect?
विकल्प
1s and 2s orbitals are spherical in shape.
The probability of finding the electron is maximum near the nucleus.
The probability of finding the electron at a given distance is equal in all directions.
The probability density of electrons for 2s orbital decreases uniformly as distance from the nucleus increases.
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उत्तर
The probability density of electrons for 2s orbital decreases uniformly as distance from the nucleus increases.
Explanation:
As per the probability density curve, the probability of finding the electrons at the 1s orbital decreases as we move far from the nucleus, however in case of 2s the probability decreases initially then it increases with the distance and thereafter at a certain point it starts decreasing with the distance.
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संबंधित प्रश्न
Choose the correct option.
“No two electrons in the same atoms can have identical set of four quantum numbers”. This statement is known as -
State Hund’s rule of maximum multiplicity with a suitable example.
Explain the anomalous behaviour of copper.
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 4, l = 2
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 3, l = 2
Write electronic configurations of \[\ce{Fe, Fe2+, Fe3+}\].
Which mineral among the following contains vanadium in it?
Which one of the following orders is CORRECT in case of energy of the given subshells?
P: n = 4; l = 3
Q: n = 5; I = 1
R: n = 5; l = 0
S: n = 4; l = 2
Which one of the following is NOT possible?
Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:
| (i) | (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2` | |
| (ii) | (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iii) | (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iv) | (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2` |
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
4s, 3s, 3p, 4d
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
5p, 4d, 5d, 4f, 6s
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
5p, 5d, 5f, 6s, 6p
Match the following species with their corresponding ground state electronic configuration.
| Atom / Ion | Electronic configuration |
| (i) \[\ce{Cu}\] | (a) 1s2 2s2 2p6 3s2 3p6 3d10 |
| (ii) \[\ce{Cu^{2+}}\] | (b) 1s2 2s2 2p6 3s2 3p6 3d10 4s2 |
| (iii) \[\ce{Zn^{2+}}\] | (c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1 |
| (iv) \[\ce{Cr^{3+}}\] | (d) 1s2 2s2 2p6 3s2 3p6 3d9 |
| (e) 1s2 2s2 2p6 3s2 3p6 3d3 |
Which of the following is the correct plot for the probability density ψ2 (r) as a function of distance 'r' of the electron from the nucleus for 2s orbitals?
Which of the following is not the permissible arrangement of electrons in an atom?
In the case of R, S configuration the group having the highest priority is ______.
Which one of the following laws will represent the pairing of electrons in a subshell after each orbital is filled with one electron?
What are the possible values of magnetic quantum number for p orbital?
