Advertisements
Advertisements
प्रश्न
Indicate the number of unpaired electrons in \[\ce{Si}\] (Z = 14).
Advertisements
उत्तर
Electronic configuration of \[\ce{Si}\] (Z = 14) is 1s2 2s2 2p6 3s2 3p2
Orbital diagram:
| ↑↓ | ↑↓ | ↑↓ | ↑↓ | ↑↓ | ↑↓ | ↑ | ↑ | |
| 1s | 2s | 2p | 3s | 3p | ||||
Number of unpaired electrons = 2
APPEARS IN
संबंधित प्रश्न
Using s, p, d notations, describe the orbital with the following quantum numbers n = 3; l =1.
Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l = 2.
Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l =3.
State Heisenberg uncertainty principle.
State and explain Pauli’s exclusion principle.
State the order of filling atomic orbitals following Aufbau principle.
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 4, l = 2
Write condensed orbital notation of electronic configuration of the following element:
Chlorine (Z = 17)
Draw shapes of 2s orbitals.
If n = 3, what are the quantum number l and m?
Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.
The principal quantum number (n) and magnetic quantum number (ml) for the valence electrons of rubidium atom (Z = 37) are ____________ respectively.
How many electrons can fit in the orbital for which n = 4 and l = 2?
Which of the following has a greater number of electrons than neutrons?
(Mass number of Mg, C, O and Na is 24, 12, 16 and 23 respectively).
Which one of the following is NOT possible?
The number of radial nodes for 3p orbital is ______.
The pair of ions having same electronic configuration is ______.
Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:
| (i) | (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2` | |
| (ii) | (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iii) | (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iv) | (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2` |
In which of the following pairs, the ions are iso-electronic?
(i) \[\ce{Na^{+}, Mg^{2+}}\]
(ii) \[\ce{Al3^{+}, O-}\]
(iii) \[\ce{Na+ , O2-}\]
(iv) \[\ce{N3-, Cl-}\]
Which of the following orbitals are degenerate?
3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
1s, 2s, 3s, 2p
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
4d, 4f, 5s, 5p
Match the following species with their corresponding ground state electronic configuration.
| Atom / Ion | Electronic configuration |
| (i) \[\ce{Cu}\] | (a) 1s2 2s2 2p6 3s2 3p6 3d10 |
| (ii) \[\ce{Cu^{2+}}\] | (b) 1s2 2s2 2p6 3s2 3p6 3d10 4s2 |
| (iii) \[\ce{Zn^{2+}}\] | (c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1 |
| (iv) \[\ce{Cr^{3+}}\] | (d) 1s2 2s2 2p6 3s2 3p6 3d9 |
| (e) 1s2 2s2 2p6 3s2 3p6 3d3 |
Match the following
| (i) Photon | (a) Value is 4 for N shell |
| (ii) Electron | (b) Probability density |
| (iii) ψ2 | (c) Always positive value |
| (iv) Principal quantum number n | (d) Exhibits both momentum and wavelength |
Match species given in Column I with the electronic configuration given in Column II.
| Column I | Column II |
| (i) \[\ce{Cr}\] | (a) [Ar]3d84s0 |
| (ii) \[\ce{Fe^{2+}}\] | (b) [Ar]3d104s1 |
| (iii) \[\ce{Ni^{2+}}\] | (c) [Ar]3d64s0 |
| (iv) \[\ce{Cu}\] | (d) [Ar] 3d54s1 |
| (e) [Ar]3d64s2 |
Which of the following element do not follow Aufbau principle?
