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Explain the anomalous behaviour of copper.

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प्रश्न

Explain the anomalous behaviour of copper.

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उत्तर

  1. Copper (Cu) has atomic number 29.
  2. Its expected electronic configuration is 1s2 2s2 2p6 3s2 3p6 4s2 3d9.
  3. The 3d orbital is neither half-filled nor fully filled. Hence, it has less stability.
  4. Due to interelectronic repulsion forces, one 4s electron enters into a 3d orbital. This makes 3d orbital completely filled and 4s orbital half-filled which gives extra stability and the electronic configuration of Cu becomes, 1s2 2s2 2p6 3s2 3p6 4s1 3d10.
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अध्याय 4: Structure of Atom - Exercises [पृष्ठ ५४]

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बालभारती Chemistry [English] Standard 11 Maharashtra State Board
अध्याय 4 Structure of Atom
Exercises | Q 6. (I) | पृष्ठ ५४

संबंधित प्रश्न

Using s, p, d notations, describe the orbital with the following quantum numbers n = 1, l = 0.


Using s, p, d notations, describe the orbital with the following quantum numbers n = 3; l =1.


Choose the correct option.

p-orbitals are _________ in shape.


State Heisenberg uncertainty principle.


Give the names of quantum numbers.


State the order of filling atomic orbitals following Aufbau principle.


Explain the anomalous behaviour of chromium.


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 2, l = 1


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 3, l = 2


Draw shapes of 2p orbitals.


Indicate the number of unpaired electrons in \[\ce{Si}\] (Z = 14).


The designation of a subshell with n = 6 and l = 2 is ____________.


Which of the following has a greater number of electrons than neutrons?

(Mass number of Mg, C, O and Na is 24, 12, 16 and 23 respectively).


Number of angular nodes for 4d orbital is ______.


Total number of orbitals associated with third shell will be ______.


Orbital angular momentum depends on ______.


The pair of ions having same electronic configuration is ______.


In which of the following pairs, the ions are iso-electronic?

(i) \[\ce{Na^{+}, Mg^{2+}}\]

(ii) \[\ce{Al3^{+}, O-}\]

(iii) \[\ce{Na+ , O2-}\]

(iv) \[\ce{N3-, Cl-}\]


Nickel atom can lose two electrons to form \[\ce{Ni^{2+}}\] ion. The atomic number of nickel is 28. From which orbital will nickel lose two electrons.


Calculate the total number of angular nodes and radial nodes present in 3p orbital.


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, arrange the following orbitals in the increasing order of energy.

5p, 4d, 5d, 4f, 6s


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, arrange the following orbitals in the increasing order of energy.

5f, 6d, 7s, 7p


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

5p, 5d, 5f, 6s, 6p


Match the following

(i) Photon (a) Value is 4 for N shell
(ii) Electron (b) Probability density
(iii) ψ2 (c) Always positive value
(iv) Principal quantum number n (d) Exhibits both momentum and wavelength

Which of the following is not the permissible arrangement of electrons in an atom?


In the case of R, S configuration the group having the highest priority is ______.


Which one of the following laws will represent the pairing of electrons in a subshell after each orbital is filled with one electron?


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