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प्रश्न
Explain the anomalous behaviour of chromium.
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उत्तर
- Chromium (Cr) has atomic number 24.
- Its expected electronic configuration is 1s2 2s2 2p6 3s2 3p6 4s2 3d4.
- The 3d orbital is less stable, as it is not half-filled.
- Due to inter-electronic repulsion forces, one 4s electron enters into the 3d orbital. This makes the 4s and 3d orbitals half-filled, which gives extra stability, and the electronic configuration of Cr becomes 1s2 2s2 2p6 3s2 3p6 4s1 3d5.
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संबंधित प्रश्न
Using s, p, d notations, describe the orbital with the following quantum numbers n = 3; l =1.
Choose the correct option.
p-orbitals are _________ in shape.
State Heisenberg uncertainty principle.
Give the names of quantum numbers.
State the order of filling atomic orbitals following Aufbau principle.
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 2, l = 1
Write condensed orbital notation of electronic configuration of the following element:
Oxygen (Z = 8)
Write condensed orbital notation of electronic configuration of the following element:
Chlorine (Z = 17)
Explain in brief, the significance of the azimuthal quantum number.
The three electrons have the following set of quantum numbers:
X = 6, 1, −1, `+1/2`
Y = 6, 0, 0, `+1/2`
Z = 5, 1, 0, `+1/2`
Identify the CORRECT statement.
How many electrons can fit in the orbital for which n = 4 and l = 2?
Which of the following has a greater number of electrons than neutrons?
(Mass number of Mg, C, O and Na is 24, 12, 16 and 23 respectively).
Which of the following options does not represent ground state electronic configuration of an atom?
The probability density plots of 1s and 2s orbitals are given in Figure:
The density of dots in a region represents the probability density of finding electrons in the region.
On the basis of above diagram which of the following statements is incorrect?
Which of the following properties of atom could be explained correctly by Thomson Model of atom?
The number of radial nodes for 3p orbital is ______.
Nickel atom can lose two electrons to form \[\ce{Ni^{2+}}\] ion. The atomic number of nickel is 28. From which orbital will nickel lose two electrons.
Calculate the total number of angular nodes and radial nodes present in 3p orbital.
Match the following species with their corresponding ground state electronic configuration.
| Atom / Ion | Electronic configuration |
| (i) \[\ce{Cu}\] | (a) 1s2 2s2 2p6 3s2 3p6 3d10 |
| (ii) \[\ce{Cu^{2+}}\] | (b) 1s2 2s2 2p6 3s2 3p6 3d10 4s2 |
| (iii) \[\ce{Zn^{2+}}\] | (c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1 |
| (iv) \[\ce{Cr^{3+}}\] | (d) 1s2 2s2 2p6 3s2 3p6 3d9 |
| (e) 1s2 2s2 2p6 3s2 3p6 3d3 |
Match the following
| (i) Photon | (a) Value is 4 for N shell |
| (ii) Electron | (b) Probability density |
| (iii) ψ2 | (c) Always positive value |
| (iv) Principal quantum number n | (d) Exhibits both momentum and wavelength |
Choose the INCORRECT statement
Which of the following is not the permissible arrangement of electrons in an atom?
In the case of R, S configuration the group having the highest priority is ______.
