हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान कक्षा ११

Which of the following statements concerning the quantum numbers are correct? (i) Angular quantum number determines the three dimensional shape of the orbital. - Chemistry

Advertisements
Advertisements

प्रश्न

Which of the following statements concerning the quantum numbers are correct?

(i) Angular quantum number determines the three dimensional shape of the orbital.

(ii) The principal quantum number determines the orientation and energy of the orbital.

(iii) Magnetic quantum number determines the size of the orbital.

(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.

टिप्पणी लिखिए
Advertisements

उत्तर

(i) Angular quantum number determines the three dimensional shape of the orbital.

(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.

Explanation:

(i) Azimuthal quantum number l is also known as orbital angular momentum or subsidiary quantum number. It determines three-dimensional shape of the orbital.

(ii) The principal quantum number determines the size of the orbit.

(iii) Magnetic quantum number determines the orientation of the electron cloud in a subshell.

(iv) An electron spins around its own’ axis, much in a similar way as earth spins around its own axis while revolving around the sun. In other words, an electron has, besides charge and mass, intrinsic spin angular quantum number.

shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 2: Structure of Atom - Multiple Choice Questions (Type - I) [पृष्ठ १८]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
अध्याय 2 Structure of Atom
Multiple Choice Questions (Type - I) | Q 21 | पृष्ठ १८

संबंधित प्रश्न

State Hund’s rule of maximum multiplicity with a suitable example.


Explain the anomalous behaviour of copper.


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 4, l = 2


Write electronic configurations of \[\ce{Fe, Fe2+, Fe3+}\].


Write condensed orbital notation of electronic configuration of the following element:

Lithium (Z = 3)


Write condensed orbital notation of electronic configuration of the following element:

Carbon (Z = 6)


Indicate the number of unpaired electron in:

Cr (Z = 24)


The principal quantum number (n) and magnetic quantum number (ml) for the valence electrons of rubidium atom (Z = 37) are ____________ respectively.


How many electrons in 19K have n = 3, l = 1?


The three electrons have the following set of quantum numbers:

X = 6, 1, −1, `+1/2`

Y = 6, 0, 0, `+1/2`

Z = 5, 1, 0, `+1/2`

Identify the CORRECT statement.


Which of the following options does not represent ground state electronic configuration of an atom?


The probability density plots of 1s and 2s orbitals are given in Figure:


The density of dots in a region represents the probability density of finding electrons in the region.

On the basis of above diagram which of the following statements is incorrect?


Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:

(i)  (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2`
   
(ii)  (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iii) (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iv)  (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2`

Which of the following sets of quantum numbers are correct?

  `n` `l` `m_l`
(i) 1 1 +2
(ii) 2 1 +1
(iii) 3 2 –2
(iv) 3 4 –2

The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, arrange the following orbitals in the increasing order of energy.

4s, 3s, 3p, 4d


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

4d, 4f, 5s, 5p


Match the following species with their corresponding ground state electronic configuration.

Atom / Ion Electronic configuration
(i) \[\ce{Cu}\] (a) 1s2 2s2 2p6 3s2 3p6 3d10
(ii) \[\ce{Cu^{2+}}\] (b) 1s2 2s2 2p6 3s2 3p6 3d10 4s2
(iii) \[\ce{Zn^{2+}}\] (c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1
(iv) \[\ce{Cr^{3+}}\] (d) 1s2 2s2 2p6 3s2 3p6 3d9
  (e) 1s2 2s2 2p6 3s2 3p6 3d3

Match species given in Column I with the electronic configuration given in Column II.

Column I Column II
(i) \[\ce{Cr}\] (a) [Ar]3d84s0
(ii) \[\ce{Fe^{2+}}\] (b) [Ar]3d104s1
(iii) \[\ce{Ni^{2+}}\] (c) [Ar]3d64s0
(iv) \[\ce{Cu}\] (d) [Ar] 3d54s1
  (e) [Ar]3d64s2

Choose the INCORRECT statement


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×