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प्रश्न
Explain the anomalous behaviour of copper.
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उत्तर
- Copper (Cu) has atomic number 29.
- Its expected electronic configuration is 1s2 2s2 2p6 3s2 3p6 4s2 3d9.
- The 3d orbital is neither half-filled nor fully filled. Hence, it has less stability.
- Due to interelectronic repulsion forces, one 4s electron enters into a 3d orbital. This makes 3d orbital completely filled and 4s orbital half-filled which gives extra stability and the electronic configuration of Cu becomes, 1s2 2s2 2p6 3s2 3p6 4s1 3d10.
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संबंधित प्रश्न
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Write a note on ‘Principal Quantum number.
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The designation of a subshell with n = 6 and l = 2 is ____________.
Which one of the following orders is CORRECT in case of energy of the given subshells?
P: n = 4; l = 3
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R: n = 5; l = 0
S: n = 4; l = 2
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Orbital angular momentum depends on ______.
The pair of ions having same electronic configuration is ______.
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(i) \[\ce{Na^{+}, Mg^{2+}}\]
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(iii) \[\ce{Na+ , O2-}\]
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Based upon the above information, solve the questions given below:
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5p, 5d, 5f, 6s, 6p
Match the quantum numbers with the information provided by these.
| Quantum number | Information provided |
| (i) Principal quantum number | (a) orientation of the orbital |
| (ii) Azimuthal quantum number | (b) energy and size of orbital |
| (iii) Magnetic quantum number | (c) spin of electron |
| (iv) Spin quantum number | (d) shape of the orbital |
Choose the INCORRECT statement
What are the possible values of magnetic quantum number for p orbital?
