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प्रश्न
Explain the anomalous behaviour of copper.
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उत्तर
- Copper (Cu) has atomic number 29.
- Its expected electronic configuration is 1s2 2s2 2p6 3s2 3p6 4s2 3d9.
- The 3d orbital is neither half-filled nor fully filled. Hence, it has less stability.
- Due to interelectronic repulsion forces, one 4s electron enters into a 3d orbital. This makes 3d orbital completely filled and 4s orbital half-filled which gives extra stability and the electronic configuration of Cu becomes, 1s2 2s2 2p6 3s2 3p6 4s1 3d10.
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संबंधित प्रश्न
Using s, p, d notations, describe the orbital with the following quantum numbers n = 3; l =1.
Choose the correct option.
Principal Quantum number describes -
Give the names of quantum numbers.
Define the term Electronic configuration.
State and explain Pauli’s exclusion principle.
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 3, l = 2
Write condensed orbital notation of electronic configuration of the following element:
Chlorine (Z = 17)
Draw shapes of 2p orbitals.
The electronic configuration of oxygen is written as 1s2 2s2 \[\ce{2p^2_{{x}}}\] \[\ce{2p^1_{{y}}}\] \[\ce{2p^1_{{z}}}\] and not as 1s2 2s2 \[\ce{2p^2_{{x}}}\], \[\ce{2p^2_{{y}}}\] \[\ce{2p^0_{{z}}}\], Explain.
Indicate the number of unpaired electron in:
Cr (Z = 24)
The principal quantum number (n) and magnetic quantum number (ml) for the valence electrons of rubidium atom (Z = 37) are ____________ respectively.
Which one of the following orders is CORRECT in case of energy of the given subshells?
P: n = 4; l = 3
Q: n = 5; I = 1
R: n = 5; l = 0
S: n = 4; l = 2
Which one of the following is NOT possible?
Which of the following options does not represent ground state electronic configuration of an atom?
The pair of ions having same electronic configuration is ______.
In which of the following pairs, the ions are iso-electronic?
(i) \[\ce{Na^{+}, Mg^{2+}}\]
(ii) \[\ce{Al3^{+}, O-}\]
(iii) \[\ce{Na+ , O2-}\]
(iv) \[\ce{N3-, Cl-}\]
Which of the following statements concerning the quantum numbers are correct?
(i) Angular quantum number determines the three dimensional shape of the orbital.
(ii) The principal quantum number determines the orientation and energy of the orbital.
(iii) Magnetic quantum number determines the size of the orbital.
(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.
Calculate the total number of angular nodes and radial nodes present in 3p orbital.
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
1s, 2s, 3s, 2p
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
4s, 3s, 3p, 4d
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
4d, 4f, 5s, 5p
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
5p, 5d, 5f, 6s, 6p
Choose the INCORRECT statement
Which of the following is not the permissible arrangement of electrons in an atom?
Which of the following element do not follow Aufbau principle?
Which one of the following laws will represent the pairing of electrons in a subshell after each orbital is filled with one electron?
