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प्रश्न
Explain the anomalous behaviour of copper.
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उत्तर
- Copper (Cu) has atomic number 29.
- Its expected electronic configuration is 1s2 2s2 2p6 3s2 3p6 4s2 3d9.
- The 3d orbital is neither half-filled nor fully filled. Hence, it has less stability.
- Due to interelectronic repulsion forces, one 4s electron enters into a 3d orbital. This makes 3d orbital completely filled and 4s orbital half-filled which gives extra stability and the electronic configuration of Cu becomes, 1s2 2s2 2p6 3s2 3p6 4s1 3d10.
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संबंधित प्रश्न
Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l = 2.
Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l =3.
State the order of filling atomic orbitals following Aufbau principle.
Write condensed orbital notation of electronic configuration of the following element:
Lithium (Z = 3)
Write condensed orbital notation of electronic configuration of the following element:
Calcium (Z = 20)
Explain in brief, the significance of the azimuthal quantum number.
Write a note on ‘Principal Quantum number.
Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.
Indicate the number of unpaired electrons in \[\ce{Si}\] (Z = 14).
The principal quantum number (n) and magnetic quantum number (ml) for the valence electrons of rubidium atom (Z = 37) are ____________ respectively.
Which one of the following orders is CORRECT in case of energy of the given subshells?
P: n = 4; l = 3
Q: n = 5; I = 1
R: n = 5; l = 0
S: n = 4; l = 2
The three electrons have the following set of quantum numbers:
X = 6, 1, −1, `+1/2`
Y = 6, 0, 0, `+1/2`
Z = 5, 1, 0, `+1/2`
Identify the CORRECT statement.
How many electrons can fit in the orbital for which n = 4 and l = 2?
Which of the following has a greater number of electrons than neutrons?
(Mass number of Mg, C, O and Na is 24, 12, 16 and 23 respectively).
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Number of angular nodes for 4d orbital is ______.
Total number of orbitals associated with third shell will be ______.
Which of the following sets of quantum numbers are correct?
| `n` | `l` | `m_l` | |
| (i) | 1 | 1 | +2 |
| (ii) | 2 | 1 | +1 |
| (iii) | 3 | 2 | –2 |
| (iv) | 3 | 4 | –2 |
Which of the following orbitals are degenerate?
3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2
Calculate the total number of angular nodes and radial nodes present in 3p orbital.
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
1s, 2s, 3s, 2p
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
4s, 3s, 3p, 4d
Match the quantum numbers with the information provided by these.
| Quantum number | Information provided |
| (i) Principal quantum number | (a) orientation of the orbital |
| (ii) Azimuthal quantum number | (b) energy and size of orbital |
| (iii) Magnetic quantum number | (c) spin of electron |
| (iv) Spin quantum number | (d) shape of the orbital |
In assigning R - S configuration, which among the following groups has highest priority?
In the case of R, S configuration the group having the highest priority is ______.
Which of the following element do not follow Aufbau principle?
Which one of the following laws will represent the pairing of electrons in a subshell after each orbital is filled with one electron?
