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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose

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प्रश्न

Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose

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उत्तर

shaalaa.com
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
2013-2014 (October)

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संबंधित प्रश्‍न

Write the reaction that indicates the presence of -CHO group in glucose


How many moles of acetic anhydride will be required to form glucose pentaacetate from 2M of glucose?

(a) 2

(b) 5

(c) 10

(d) 2.5


What happens when glucose is treated with hydroxylamine?


Glucose on reaction with HI gives n-hexane. What does it suggest about the structure of glucose?

 

 

The following compound can be called as:


Choose the appropriate answer(s) for the below representation from the options given


Which of the following statements is incorrect regarding glucose?


The symbols D and L represents ____________.


Which one of the following compounds is different from the rest?


Glucose is found to exist in two different α and β crystalline forms. These forms can be obtained by:

(i) The α form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(ii) The β form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(iii) The β form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.

(iv) The α form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.


The reaction of glucose with red P + HI is called ____________.


Which is the least stable form of glucose?


A solution of D-glucose in water rotates the plane polarised light ____________.


The number of chiral carbon atoms present in cyclic structure α-D(+) glucose:


The number of chiral carbons in ß-D(+) glucose is ____________.


Which of the following pairs represents anomers?


Why does compound (A) given below not form an oxime?


                   (A)


How will you distinguish 1° and 2° hydroxyl groups present in glucose? Explain with reactions.


Assertion: D (+) – Glucose is dextrorotatory in nature.

Reason: ‘D’ represents its dextrorotatory nature.


Write the reactions of D-glucose which can’t be explained by its open-chain structure. How can cyclic structure of glucose explain these reactions?


What happens when D-glucose is treated with the following reagent?

HI


Account for the following:

There are 5 OH groups in glucose


Account for the following:

What happens when D – glucose is treated with the following reagents

HNO3


Consider the following reactions:

(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]

(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]

(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]

'X, 'Y' and 'Z' in these reactions are respectively:


Match List - I with List - II.

  List I   List II
(A) Glucose + HI (I) Gluconic acid
(B) Glucose + Br2 water (II) Glucose pentacetate
(C) Glucose + acetic anhydride (III) Saccharic acid
(D) Glucose + HNO3 (IV) Hexane

Choose the correct answer from the options given below:


When D-glucose reacts with HI, it forms ______.


Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction?


The reagents with which glucose does not react to give the corresponding tests/products are:

  1. Tollen’s reagent
  2. Schiff’s reagent
  3. HCN
  4. NH2OH
  5. NaHSO3

Choose the correct options from the given below:


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