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प्रश्न
Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose
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उत्तर
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संबंधित प्रश्न
How many moles of acetic anhydride will be required to form glucose pentaacetate from 2M of glucose?
(a) 2
(b) 5
(c) 10
(d) 2.5
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
Enlist the properties of glucose that can not be explained on the basis of open chain structure of it
Glucose on reaction with HI gives n-hexane. What does it suggest about the structure of glucose?
Fill in the blanks by choosing the appropriate word/words from those given in the brackets:
(iodoform, acetaldehyde, positive, greater, acidic, acetone, disaccharide, negative, increases, glucose, decreases, chloroform, polysaccharide, lactose, lesser, basic, cationic hydrolysis, anionic hydrolysis)
Sucrose is a _________ and yields upon hydrolysis, a mixture of ________ and fructose.
Write the reaction involved when D-glucose is treated with the following reagent:
(CH3CO)2O
The spatial arrangement of the given molecule is denoted by:
Acetylation of glucose yields ____________.
Glucose does not give Schiff’s test because of the formation of cyclic ____________.
Which of the following properties of glucose cannot be explained by its open chain structure?
(i) Glucose does not form hydrogen sulphite with NaHSO3.
(ii) On oxidation with HNO3 glucose gives saccharic acid.
(iii) Glucose is found to exist in two different crystalline forms which are named as α and β.
Glucose is found to exist in two different α and β crystalline forms. These forms can be obtained by:
(i) The α form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.
(ii) The β form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.
(iii) The β form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.
(iv) The α form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.
Reduction of glucose by HI suggest that ____________.
The reaction of glucose with red P + HI is called ____________.
Which is the least stable form of glucose?
Which one is correct?
In the following reaction, identify A and B:
\[\begin{array}{cc}
\ce{C6H12O6 ->[Acetic anhydride] A}\\
\downarrow \text{Conc. nitric acid}\phantom{...}\\
\ce{B}\phantom{.................}\end{array}\]
Which of the following pairs represents anomers?
Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
| (I) |  |
| (II) |  |
| (III) |  |
Assertion: D (+) – Glucose is dextrorotatory in nature.
Reason: ‘D’ represents its dextrorotatory nature.
Write the reactions of D-glucose which can’t be explained by its open-chain structure. How can cyclic structure of glucose explain these reactions?
What happens when D-glucose is treated with the following reagent?
HI
Account for the following:
What happens when D – glucose is treated with the following reagents
Bromine water
Glucose with excess of phenyl hydrazine forms ______.
Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction?
