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प्रश्न
Why does compound (A) given below not form an oxime?
(A)
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उत्तर
Glucose pentaacetate (structure A) does not have a free –OH group at C, and therefore, cannot be converted to the open chain form to give a free –CHO group and hence it does not form the oxime.
(Structure A)
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संबंधित प्रश्न
How many moles of acetic anhydride will be required to form glucose pentaacetate from 2M of glucose?
(a) 2
(b) 5
(c) 10
(d) 2.5
What happens when glucose is treated with hydroxylamine?
The spatial arrangement of the given molecule is denoted by:
Which one of the following compounds is different from the rest?
When glucose reacts with bromine water, the main product is ____________.
Glucose does not react with ____________.
The number of chiral carbon atoms present in cyclic structure α-D(+) glucose:
Choose the correct relationship for glucose and fructose:
Which one of the following reactions is not explained by the open chain Structure of glucose?
Which of the following pairs represents anomers?
On the basis of which evidences D-glucose was assigned the following structure?
\[\begin{array}{cc}
\ce{CHO}\\
|\phantom{....}\\
\phantom{..}\ce{(CHOH)4}\\
|\phantom{....}\\
\phantom{..}\ce{CH2OH}
\end{array}\]
Account for the following:
What happens when D – glucose is treated with the following reagents
Bromine water
Consider the following reactions:
(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]
(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]
(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]
'X, 'Y' and 'Z' in these reactions are respectively:
Glucose with excess of phenyl hydrazine forms ______.
Match List - I with List - II.
| List I | List II | ||
| (A) | Glucose + HI | (I) | Gluconic acid |
| (B) | Glucose + Br2 water | (II) | Glucose pentacetate |
| (C) | Glucose + acetic anhydride | (III) | Saccharic acid |
| (D) | Glucose + HNO3 | (IV) | Hexane |
Choose the correct answer from the options given below:
Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction?
Give a reason for the following observations:
Penta-acetate of glucose does not react with hydroxylamine.
The reagents with which glucose does not react to give the corresponding tests/products are:
- Tollen’s reagent
- Schiff’s reagent
- HCN
- NH2OH
- NaHSO3
Choose the correct options from the given below:
