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प्रश्न
Which of the following reactions of glucose can be explained only by its cyclic structure?
विकल्प
Glucose forms pentaacetate
Glucose reacts with hydroxylamine to form an oxime
Pentaacetate of glucose does not react with hydroxylamine
Glucose is oxidised by nitric acid to gluconic acid
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उत्तर
Pentaacetate of glucose does not react with hydroxylamine
Explanation:
The pentaacetate of glucose does not react with hydroxylamine indicating the absence of free –CHO group. This property of glucose can be explained only by its cyclic structure.
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संबंधित प्रश्न
Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose
What happens when glucose is treated with hydroxylamine?
What do you observe when glucose is treated with bromine water?
Write the reaction involved when D-glucose is treated with the following reagent:
(CH3CO)2O
The following compound can be called as:
Glucose does not give Schiff’s test because of the formation of cyclic ____________.
Which of the following statements is incorrect regarding glucose?
Glucose does not react with ____________.
Glucose reacts with acetic anhydride to form ______.
Glucose is found to exist in two different α and β crystalline forms. These forms can be obtained by:
(i) The α form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.
(ii) The β form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.
(iii) The β form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.
(iv) The α form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.
A solution of D-glucose in water rotates the plane polarised light ____________.
Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
| (I) |  |
| (II) |  |
| (III) |  |
How will you distinguish 1° and 2° hydroxyl groups present in glucose? Explain with reactions.
Assertion: D (+) – Glucose is dextrorotatory in nature.
Reason: ‘D’ represents its dextrorotatory nature.
On the basis of which evidences D-glucose was assigned the following structure?
\[\begin{array}{cc}
\ce{CHO}\\
|\phantom{....}\\
\phantom{..}\ce{(CHOH)4}\\
|\phantom{....}\\
\phantom{..}\ce{CH2OH}
\end{array}\]
Account for the following:
What happens when D – glucose is treated with the following reagents
Bromine water
Match List - I with List - II.
| List I | List II | ||
| (A) | Glucose + HI | (I) | Gluconic acid |
| (B) | Glucose + Br2 water | (II) | Glucose pentacetate |
| (C) | Glucose + acetic anhydride | (III) | Saccharic acid |
| (D) | Glucose + HNO3 | (IV) | Hexane |
Choose the correct answer from the options given below:
Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction?
Give a reason for the following observations:
Penta-acetate of glucose does not react with hydroxylamine.
