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प्रश्न
Account for the following:
What happens when D – glucose is treated with the following reagents
HNO3
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उत्तर
\[\begin{array}{cc}
\phantom{......}\ce{CHO}\phantom{.............}\ce{COOH}\phantom{.............}\ce{COOH}\phantom{......}\\
\phantom{...}|\phantom{..................}|\phantom{...................}|\phantom{........}\\
\phantom{.}\ce{(CHOH)4 ->[Oxidation] (CHOH)4 <-[Oxidation] (CHOH)4}\\
\phantom{...}|\phantom{..................}|\phantom{...................}|\phantom{........}\\
\phantom{.....}\ce{CH2OH}\phantom{...........}\ce{\underset{\underset{acid}{Saccharic}}{COOH}}\phantom{.............}\ce{\underset{\underset{acid}{Gluconic}}{CH2OH}}\phantom{....}
\end{array}\]
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संबंधित प्रश्न
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
Write the reaction involved when D-glucose is treated with the following reagent:
Br2 water
What is the most abundant organic compound on earth?
The number of chiral carbon atoms present in cyclic structure α-D(+) glucose:
Which one is correct?
Why does compound (A) given below not form an oxime?
(A)
Write the reactions of D-glucose which can’t be explained by its open-chain structure. How can cyclic structure of glucose explain these reactions?
Consider the following reactions:
(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]
(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]
(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]
'X, 'Y' and 'Z' in these reactions are respectively:
Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction?
The reagents with which glucose does not react to give the corresponding tests/products are:
- Tollen’s reagent
- Schiff’s reagent
- HCN
- NH2OH
- NaHSO3
Choose the correct options from the given below:
