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प्रश्न
Account for the following:
What happens when D – glucose is treated with the following reagents
HNO3
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उत्तर
\[\begin{array}{cc}
\phantom{......}\ce{CHO}\phantom{.............}\ce{COOH}\phantom{.............}\ce{COOH}\phantom{......}\\
\phantom{...}|\phantom{..................}|\phantom{...................}|\phantom{........}\\
\phantom{.}\ce{(CHOH)4 ->[Oxidation] (CHOH)4 <-[Oxidation] (CHOH)4}\\
\phantom{...}|\phantom{..................}|\phantom{...................}|\phantom{........}\\
\phantom{.....}\ce{CH2OH}\phantom{...........}\ce{\underset{\underset{acid}{Saccharic}}{COOH}}\phantom{.............}\ce{\underset{\underset{acid}{Gluconic}}{CH2OH}}\phantom{....}
\end{array}\]
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संबंधित प्रश्न
Differentiable between the following:
Amylose and Amylopectin
Fill in the blanks by choosing the appropriate word/words from those given in the brackets:
(iodoform, acetaldehyde, positive, greater, acidic, acetone, disaccharide, negative, increases, glucose, decreases, chloroform, polysaccharide, lactose, lesser, basic, cationic hydrolysis, anionic hydrolysis)
Sucrose is a _________ and yields upon hydrolysis, a mixture of ________ and fructose.
Choose the appropriate answer(s) for the below representation from the options given
Glucose reacts with acetic anhydride to form ______.
A solution of D-glucose in water rotates the plane polarised light ____________.
Choose the correct relationship for glucose and fructose:
The number of chiral carbons in ß-D(+) glucose is ____________.
Which of the following pairs represents anomers?
Assertion: D (+) – Glucose is dextrorotatory in nature.
Reason: ‘D’ represents its dextrorotatory nature.
Consider the following reactions:
(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]
(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]
(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]
'X, 'Y' and 'Z' in these reactions are respectively:
