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Question
Account for the following:
What happens when D – glucose is treated with the following reagents
HNO3
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Solution
\[\begin{array}{cc}
\phantom{......}\ce{CHO}\phantom{.............}\ce{COOH}\phantom{.............}\ce{COOH}\phantom{......}\\
\phantom{...}|\phantom{..................}|\phantom{...................}|\phantom{........}\\
\phantom{.}\ce{(CHOH)4 ->[Oxidation] (CHOH)4 <-[Oxidation] (CHOH)4}\\
\phantom{...}|\phantom{..................}|\phantom{...................}|\phantom{........}\\
\phantom{.....}\ce{CH2OH}\phantom{...........}\ce{\underset{\underset{acid}{Saccharic}}{COOH}}\phantom{.............}\ce{\underset{\underset{acid}{Gluconic}}{CH2OH}}\phantom{....}
\end{array}\]
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RELATED QUESTIONS
Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose
Enlist the properties of glucose that can not be explained on the basis of open chain structure of it
Fill in the blanks by choosing the appropriate word/words from those given in the brackets:
(iodoform, acetaldehyde, positive, greater, acidic, acetone, disaccharide, negative, increases, glucose, decreases, chloroform, polysaccharide, lactose, lesser, basic, cationic hydrolysis, anionic hydrolysis)
Sucrose is a _________ and yields upon hydrolysis, a mixture of ________ and fructose.
Which of the following statements is incorrect regarding glucose?
Which of the following properties of glucose cannot be explained by its open chain structure?
(i) Glucose does not form hydrogen sulphite with NaHSO3.
(ii) On oxidation with HNO3 glucose gives saccharic acid.
(iii) Glucose is found to exist in two different crystalline forms which are named as α and β.
The number of chiral carbons in ß-D(+) glucose is ____________.
Why does compound (A) given below not form an oxime?
(A)
Assertion: D (+) – Glucose is dextrorotatory in nature.
Reason: ‘D’ represents its dextrorotatory nature.
What happens when D-glucose is treated with the following reagent?
HI
Give a reason for the following observations:
Penta-acetate of glucose does not react with hydroxylamine.
