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प्रश्न
Write the reaction involved when D-glucose is treated with the following reagent:
(CH3CO)2O
Write the reaction when D-glucose reacts with the following:
Acetic anhydride
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उत्तर
\[\begin{array}{cc}
\phantom{.}\ce{CHO}\phantom{........................................}\ce{CHO}\phantom{...................}\\
|\phantom{...............................................}|\phantom{......................}\\
\phantom{.....................}\ce{(CHOH)4 + \underset{Acetic anhydride}{5(CH3CO)2O}->(CHOCOCH3)4 + 5CH3COOH}\\
|\phantom{...............................................}|\phantom{......................}\\
\phantom{...}\ce{\underset{\text{D-glucose}}{CH2OH}}\phantom{...................................}\ce{CH2O-C-CH3}\phantom{....}\\
\phantom{..................................................}||\\
\phantom{..................................................}\ce{\underset{\text{Glucose penta acetate}}{O}}
\end{array}\]
संबंधित प्रश्न
What happens when glucose is treated with hydroxylamine?
The following compound can be called as:
The spatial arrangement of the given molecule is denoted by:
Which one of the following compounds is different from the rest?
Which one of the following reactions is not explained by the open chain Structure of glucose?
How will you distinguish 1° and 2° hydroxyl groups present in glucose? Explain with reactions.
Assertion: D (+) – Glucose is dextrorotatory in nature.
Reason: ‘D’ represents its dextrorotatory nature.
What happens when D-glucose is treated with the following reagent?
HI
Consider the following reactions:
(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]
(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]
(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]
'X, 'Y' and 'Z' in these reactions are respectively:
Glucose with excess of phenyl hydrazine forms ______.
