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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write the reaction that indicates the presence of -CHO group in glucose

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प्रश्न

Write the reaction that indicates the presence of -CHO group in glucose

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उत्तर

The oxidation of glucose with bromine water (which is a mild oxidizing agent) forms gluconic acid. This indicates presence of aldehyde group.

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2013-2014 (October)

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संबंधित प्रश्‍न

Write the product when D-glucose reacts with conc. HNO3.


What do you observe when glucose solution is heated with Tollen’s reagent?


What do you observe when glucose is treated with bromine water?


The following compound can be called as:


The number of asymmetric carbon atom(s) below the figure is/are


Oxime is formed by treating glucose with ____________.


Glucose does not give Schiff’s test because of the formation of cyclic ____________.


The symbols D and L represents ____________.


When glucose reacts with bromine water, the main product is ____________.


Glucose does not react with ____________.


Which of the following properties of glucose cannot be explained by its open chain structure?

(i) Glucose does not form hydrogen sulphite with NaHSO3.

(ii) On oxidation with HNO3 glucose gives saccharic acid.

(iii) Glucose is found to exist in two different crystalline forms which are named as α and β.


Glucose is found to exist in two different α and β crystalline forms. These forms can be obtained by:

(i) The α form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(ii) The β form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(iii) The β form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.

(iv) The α form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.


The two forms of D-glucopyranose obtained from the solution of D-glucose are called ____________.


The letter D and L in carbohydrates represent ____________.


The number of chiral carbons in ß-D(+) glucose is ____________.


In the following reaction, identify A and B:

\[\begin{array}{cc}
\ce{C6H12O6 ->[Acetic anhydride] A}\\
\downarrow \text{Conc. nitric acid}\phantom{...}\\
\ce{B}\phantom{.................}\end{array}\]


Which of the following pairs represents anomers?


Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?

(I)
(II)
(III)

Assertion: D (+) – Glucose is dextrorotatory in nature.

Reason: ‘D’ represents its dextrorotatory nature.


Write the reactions of D-glucose which can’t be explained by its open-chain structure. How can cyclic structure of glucose explain these reactions?


Account for the following:

There are 5 OH groups in glucose


Account for the following:

What happens when D – glucose is treated with the following reagents

Bromine water


Account for the following:

What happens when D – glucose is treated with the following reagents

HNO3


When D-glucose reacts with HI, it forms ______.


The reagents with which glucose does not react to give the corresponding tests/products are:

  1. Tollen’s reagent
  2. Schiff’s reagent
  3. HCN
  4. NH2OH
  5. NaHSO3

Choose the correct options from the given below:


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