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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write the reaction that indicates the presence of -CHO group in glucose

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प्रश्न

Write the reaction that indicates the presence of -CHO group in glucose

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उत्तर

The oxidation of glucose with bromine water (which is a mild oxidizing agent) forms gluconic acid. This indicates presence of aldehyde group.

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2013-2014 (October)

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संबंधित प्रश्‍न

Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose


Enlist the properties of glucose that can not be explained on the basis of open chain structure of it


Write the product when D-glucose reacts with conc. HNO3.


Fill in the blanks by choosing the appropriate word/words from those given in the brackets:  

(iodoform, acetaldehyde, positive, greater, acidic, acetone, disaccharide, negative, increases, glucose, decreases, chloroform, polysaccharide, lactose, lesser, basic, cationic hydrolysis, anionic hydrolysis)

Sucrose is a _________ and yields upon hydrolysis, a mixture of ________ and fructose.


Write the reaction involved when D-glucose is treated with the following reagent:

(CH3CO)2O


The spatial arrangement of the given molecule is denoted by:


Choose the appropriate answer(s) for the below representation from the options given


What is the most abundant organic compound on earth?


Oxime is formed by treating glucose with ____________.


Acetylation of glucose yields ____________.


Which of the following statements is incorrect regarding glucose?


When glucose reacts with bromine water, the main product is ____________.


Glucose reacts with acetic anhydride to form ______.


Which of the following properties of glucose cannot be explained by its open chain structure?

(i) Glucose does not form hydrogen sulphite with NaHSO3.

(ii) On oxidation with HNO3 glucose gives saccharic acid.

(iii) Glucose is found to exist in two different crystalline forms which are named as α and β.


Glucose is found to exist in two different α and β crystalline forms. These forms can be obtained by:

(i) The α form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(ii) The β form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(iii) The β form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.

(iv) The α form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.


The number of chiral carbon atoms present in cyclic structure α-D(+) glucose:


Choose the correct relationship for glucose and fructose:


In the following reaction, identify A and B:

\[\begin{array}{cc}
\ce{C6H12O6 ->[Acetic anhydride] A}\\
\downarrow \text{Conc. nitric acid}\phantom{...}\\
\ce{B}\phantom{.................}\end{array}\]


Which of the following pairs represents anomers?


Why does compound (A) given below not form an oxime?


                   (A)


Assertion: D (+) – Glucose is dextrorotatory in nature.

Reason: ‘D’ represents its dextrorotatory nature.


Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction?


Give a reason for the following observations:

Penta-acetate of glucose does not react with hydroxylamine.


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