हिंदी

Write the reaction that indicates the presence of -CHO group in glucose

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प्रश्न

Write the reaction that indicates the presence of -CHO group in glucose

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उत्तर

The oxidation of glucose with bromine water (which is a mild oxidizing agent) forms gluconic acid. This indicates presence of aldehyde group.

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2013-2014 (October)

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संबंधित प्रश्न

Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose


Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.


Maltose is a 

(a) Polysaccharide

(b) Disaccharide

(c) Trisaccharide

(d) Monosaccharide


Enlist the properties of glucose that can not be explained on the basis of open chain structure of it


Write the product when D-glucose reacts with conc. HNO3.


Differentiable between the following: 
Amylose and Amylopectin 


Answer the following question.
What is the basic structural difference between glucose and fructose?


Write the reaction involved when D-glucose is treated with the following reagent:

(CH3CO)2O


The number of asymmetric carbon atom(s) below the figure is/are


Which of the following statements is incorrect regarding glucose?


Reduction of glucose by HI suggest that ____________.


The number of chiral carbon atoms present in cyclic structure α-D(+) glucose:


The α-D glucose and β-D glucose differ from each other due to difference in carbon atom with respect to its ____________.


The number of chiral carbons in ß-D(+) glucose is ____________.


Which one is correct?


Which one of the following reactions is not explained by the open chain Structure of glucose?


In the following reaction, identify A and B:

\[\begin{array}{cc}
\ce{C6H12O6 ->[Acetic anhydride] A}\\
\downarrow \text{Conc. nitric acid}\phantom{...}\\
\ce{B}\phantom{.................}\end{array}\]


Which of the following pairs represents anomers?


Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?

(I)
(II)
(III)

How will you distinguish 1° and 2° hydroxyl groups present in glucose? Explain with reactions.


Assertion: D (+) – Glucose is dextrorotatory in nature.

Reason: ‘D’ represents its dextrorotatory nature.


Write the reactions of D-glucose which can’t be explained by its open-chain structure. How can cyclic structure of glucose explain these reactions?


What happens when D-glucose is treated with the following reagent?

HI


Account for the following:

What happens when D – glucose is treated with the following reagents

HNO3


Consider the following reactions:

(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]

(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]

(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]

'X, 'Y' and 'Z' in these reactions are respectively:


Give a reason for the following observations:

Penta-acetate of glucose does not react with hydroxylamine.


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