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Write the reaction that indicates the presence of -CHO group in glucose - Chemistry

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प्रश्न

Write the reaction that indicates the presence of -CHO group in glucose

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उत्तर

The oxidation of glucose with bromine water (which is a mild oxidizing agent) forms gluconic acid. This indicates presence of aldehyde group.

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2013-2014 (October)

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संबंधित प्रश्न

Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose


How many moles of acetic anhydride will be required to form glucose pentaacetate from 2M of glucose?

(a) 2

(b) 5

(c) 10

(d) 2.5


Enlist the properties of glucose that can not be explained on the basis of open chain structure of it


Differentiable between the following: 
Amylose and Amylopectin 


Answer the following question.
What is the basic structural difference between glucose and fructose?


What is the most abundant organic compound on earth?


Oxime is formed by treating glucose with ____________.


Acetylation of glucose yields ____________.


Glucose does not give Schiff’s test because of the formation of cyclic ____________.


Which of the following statements is incorrect regarding glucose?


When glucose reacts with bromine water, the main product is ____________.


Glucose does not react with ____________.


Glucose reacts with acetic anhydride to form ______.


Reduction of glucose by HI suggest that ____________.


Which is the least stable form of glucose?


Which one is correct?


Which one of the following reactions is not explained by the open chain Structure of glucose?


On the basis of which evidences D-glucose was assigned the following structure?

\[\begin{array}{cc}
\ce{CHO}\\
|\phantom{....}\\
\phantom{..}\ce{(CHOH)4}\\
|\phantom{....}\\
\phantom{..}\ce{CH2OH}
\end{array}\]


What happens when D-glucose is treated with the following reagent?

HI


Account for the following:

What happens when D – glucose is treated with the following reagents

Bromine water


Consider the following reactions:

(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]

(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]

(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]

'X, 'Y' and 'Z' in these reactions are respectively:


Glucose with excess of phenyl hydrazine forms ______.


The number of asymmetric carbon atoms in the glucose molecule in open and cyclic form is ______.


When D-glucose reacts with HI, it forms ______.


The reagents with which glucose does not react to give the corresponding tests/products are:

  1. Tollen’s reagent
  2. Schiff’s reagent
  3. HCN
  4. NH2OH
  5. NaHSO3

Choose the correct options from the given below:


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