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Write the reaction that indicates the presence of -CHO group in glucose - Chemistry

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प्रश्न

Write the reaction that indicates the presence of -CHO group in glucose

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उत्तर

The oxidation of glucose with bromine water (which is a mild oxidizing agent) forms gluconic acid. This indicates presence of aldehyde group.

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2013-2014 (October)

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संबंधित प्रश्न

Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose


Enlist the properties of glucose that can not be explained on the basis of open chain structure of it


Write the product when D-glucose reacts with conc. HNO3.


Glucose on reaction with HI gives n-hexane. What does it suggest about the structure of glucose?

 

 

What do you observe when glucose solution is heated with Tollen’s reagent?


Fill in the blanks by choosing the appropriate word/words from those given in the brackets:  

(iodoform, acetaldehyde, positive, greater, acidic, acetone, disaccharide, negative, increases, glucose, decreases, chloroform, polysaccharide, lactose, lesser, basic, cationic hydrolysis, anionic hydrolysis)

Sucrose is a _________ and yields upon hydrolysis, a mixture of ________ and fructose.


What do you observe when glucose is treated with bromine water?


Answer the following question.
What is the basic structural difference between glucose and fructose?


Write the reaction involved when D-glucose is treated with the following reagent:

Br2 water


Write the reactions involved when D-glucose is treated with the following reagent:
H2N-OH


The number of asymmetric carbon atom(s) below the figure is/are


Which one of the following compounds is different from the rest?


Glucose does not react with ____________.


Glucose reacts with acetic anhydride to form ______.


Which of the following reactions of glucose can be explained only by its cyclic structure?


A solution of D-glucose in water rotates the plane polarised light ____________.


The two forms of D-glucopyranose obtained from the solution of D-glucose are called ____________.


Which one of the following reactions is not explained by the open chain Structure of glucose?


Why does compound (A) given below not form an oxime?


                   (A)


Assertion: D (+) – Glucose is dextrorotatory in nature.

Reason: ‘D’ represents its dextrorotatory nature.


Account for the following:

What happens when D – glucose is treated with the following reagents

Bromine water


Account for the following:

What happens when D – glucose is treated with the following reagents

HNO3


Consider the following reactions:

(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]

(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]

(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]

'X, 'Y' and 'Z' in these reactions are respectively:


Give a reason for the following observations:

Penta-acetate of glucose does not react with hydroxylamine.


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