Advertisements
Advertisements
प्रश्न
Give a reason for the following observations:
Penta-acetate of glucose does not react with hydroxylamine.
Advertisements
उत्तर
Penta-acetate of glucose does not react with hydroxylamine (−OHNH2) because there is no free −CHO group present.
APPEARS IN
संबंधित प्रश्न
What happens when glucose is treated with hydroxylamine?
Maltose is a
(a) Polysaccharide
(b) Disaccharide
(c) Trisaccharide
(d) Monosaccharide
What do you observe when glucose solution is heated with Tollen’s reagent?
Fill in the blanks by choosing the appropriate word/words from those given in the brackets:
(iodoform, acetaldehyde, positive, greater, acidic, acetone, disaccharide, negative, increases, glucose, decreases, chloroform, polysaccharide, lactose, lesser, basic, cationic hydrolysis, anionic hydrolysis)
Sucrose is a _________ and yields upon hydrolysis, a mixture of ________ and fructose.
Write the reaction involved when D-glucose is treated with the following reagent:
Br2 water
Glucose does not give Schiff’s test because of the formation of cyclic ____________.
Glucose is found to exist in two different α and β crystalline forms. These forms can be obtained by:
(i) The α form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.
(ii) The β form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.
(iii) The β form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.
(iv) The α form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.
On the basis of which evidences D-glucose was assigned the following structure?
\[\begin{array}{cc}
\ce{CHO}\\
|\phantom{....}\\
\phantom{..}\ce{(CHOH)4}\\
|\phantom{....}\\
\phantom{..}\ce{CH2OH}
\end{array}\]
Account for the following:
There are 5 OH groups in glucose
Consider the following reactions:
(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]
(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]
(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]
'X, 'Y' and 'Z' in these reactions are respectively:
