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प्रश्न
What happens when D-glucose is treated with the following reagent?
HI
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उत्तर
When D-glucose is heated with HI for a long time, n-hexane is formed.
\[\begin{array}{cc}
\ce{CHO}\phantom{...............................................}\\
|\phantom{..................................................}\\
\ce{(CHOH)4 ->[HI][\Delta] \underset{n-hexane}{CH3 - CH2 - CH2 - CH2 - CH2 - CH3}}\\
|\phantom{..................................................}\\
\ce{\underset{{D-glucose}}{CH2OH}}\phantom{..........................................}
\end{array}\]
APPEARS IN
संबंधित प्रश्न
Write the reaction that indicates the presence of -CHO group in glucose
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
Write the product when D-glucose reacts with conc. HNO3.
Glucose on reaction with HI gives n-hexane. What does it suggest about the structure of glucose?
Fill in the blanks by choosing the appropriate word/words from those given in the brackets:
(iodoform, acetaldehyde, positive, greater, acidic, acetone, disaccharide, negative, increases, glucose, decreases, chloroform, polysaccharide, lactose, lesser, basic, cationic hydrolysis, anionic hydrolysis)
Sucrose is a _________ and yields upon hydrolysis, a mixture of ________ and fructose.
Which of the following statements is incorrect regarding glucose?
Which one of the following compounds is different from the rest?
Glucose reacts with acetic anhydride to form ______.
The reaction of glucose with red P + HI is called ____________.
Which is the least stable form of glucose?
The letter D and L in carbohydrates represent ____________.
Which one of the following reactions is not explained by the open chain Structure of glucose?
Which of the following pairs represents anomers?
How will you distinguish 1° and 2° hydroxyl groups present in glucose? Explain with reactions.
Account for the following:
What happens when D – glucose is treated with the following reagents
Bromine water
Consider the following reactions:
(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]
(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]
(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]
'X, 'Y' and 'Z' in these reactions are respectively:
Give a reason for the following observations:
Penta-acetate of glucose does not react with hydroxylamine.
