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प्रश्न
Write the reaction involved when D-glucose is treated with the following reagent:
Br2 water
What happens when D-glucose is treated with the following reagent?
Bromine water
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उत्तर
When glucose is heated with bromine water, it is oxidised to gluconic acid, a six-carbon carboxylic acid.
\[\begin{array}{cc}
\phantom{......}\ce{CHO}\phantom{.....................}\ce{COOH}\phantom{}\\
|\phantom{............................}|\phantom{..}\\
\phantom{.......}\ce{(CHOH)4->[Br2 water](CHOH)4}\\
|\phantom{............................}|\phantom{..}\\
\phantom{.............}\ce{\underset{\text{D-glucose}}{CH2OH}}\phantom{...............}\ce{\underset{\text{D-gluconic acid}}{CH2OH}}\phantom{....}
\end{array}\]
संबंधित प्रश्न
Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose
How many moles of acetic anhydride will be required to form glucose pentaacetate from 2M of glucose?
(a) 2
(b) 5
(c) 10
(d) 2.5
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
Enlist the properties of glucose that can not be explained on the basis of open chain structure of it
What do you observe when glucose solution is heated with Tollen’s reagent?
What do you observe when glucose is treated with bromine water?
Glucose does not give Schiff’s test because of the formation of cyclic ____________.
Which of the following statements is incorrect regarding glucose?
The symbols D and L represents ____________.
Which of the following properties of glucose cannot be explained by its open chain structure?
(i) Glucose does not form hydrogen sulphite with NaHSO3.
(ii) On oxidation with HNO3 glucose gives saccharic acid.
(iii) Glucose is found to exist in two different crystalline forms which are named as α and β.
Glucose is found to exist in two different α and β crystalline forms. These forms can be obtained by:
(i) The α form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.
(ii) The β form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.
(iii) The β form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.
(iv) The α form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.
A solution of D-glucose in water rotates the plane polarised light ____________.
Assertion: D (+) – Glucose is dextrorotatory in nature.
Reason: ‘D’ represents its dextrorotatory nature.
Write the reactions of D-glucose which can’t be explained by its open-chain structure. How can cyclic structure of glucose explain these reactions?
Account for the following:
There are 5 OH groups in glucose
Account for the following:
What happens when D – glucose is treated with the following reagents
HNO3
The reagents with which glucose does not react to give the corresponding tests/products are:
- Tollen’s reagent
- Schiff’s reagent
- HCN
- NH2OH
- NaHSO3
Choose the correct options from the given below:
