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What Happens When Glucose is Treated with Hydroxylamine?

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प्रश्न

What happens when glucose is treated with hydroxylamine?

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उत्तर

Action of hydroxylamine (NH2OH) on glucose: The reaction of glucose with
hydroxylamine gives an oxime. This indicates the presence of carbonyl group.

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2016-2017 (July)

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संबंधित प्रश्न

Draw the simple Fisher projection formulae of D - (+) - glucose and D - (-) - fructose


Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.


Maltose is a 

(a) Polysaccharide

(b) Disaccharide

(c) Trisaccharide

(d) Monosaccharide


Write the product when D-glucose reacts with conc. HNO3.


Fill in the blanks by choosing the appropriate word/words from those given in the brackets:  

(iodoform, acetaldehyde, positive, greater, acidic, acetone, disaccharide, negative, increases, glucose, decreases, chloroform, polysaccharide, lactose, lesser, basic, cationic hydrolysis, anionic hydrolysis)

Sucrose is a _________ and yields upon hydrolysis, a mixture of ________ and fructose.


What do you observe when glucose is treated with bromine water?


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What is the basic structural difference between glucose and fructose?


Write the reaction involved when D-glucose is treated with the following reagent:

Br2 water


Write the reaction involved when D-glucose is treated with the following reagent:

(CH3CO)2O


The spatial arrangement of the given molecule is denoted by:


Choose the appropriate answer(s) for the below representation from the options given


What is the most abundant organic compound on earth?


Acetylation of glucose yields ____________.


Glucose does not give Schiff’s test because of the formation of cyclic ____________.


Which of the following statements is incorrect regarding glucose?


Glucose does not react with ____________.


Which of the following properties of glucose cannot be explained by its open chain structure?

(i) Glucose does not form hydrogen sulphite with NaHSO3.

(ii) On oxidation with HNO3 glucose gives saccharic acid.

(iii) Glucose is found to exist in two different crystalline forms which are named as α and β.


Glucose is found to exist in two different α and β crystalline forms. These forms can be obtained by:

(i) The α form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(ii) The β form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(iii) The β form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.

(iv) The α form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.


A solution of D-glucose in water rotates the plane polarised light ____________.


The number of chiral carbon atoms present in cyclic structure α-D(+) glucose:


The two forms of D-glucopyranose obtained from the solution of D-glucose are called ____________.


The letter D and L in carbohydrates represent ____________.


Which one is correct?


Which one of the following reactions is not explained by the open chain Structure of glucose?


Assertion: D (+) – Glucose is dextrorotatory in nature.

Reason: ‘D’ represents its dextrorotatory nature.


Account for the following:

What happens when D – glucose is treated with the following reagents

HNO3


Consider the following reactions:

(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]

(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]

(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]

'X, 'Y' and 'Z' in these reactions are respectively:


Match List - I with List - II.

  List I   List II
(A) Glucose + HI (I) Gluconic acid
(B) Glucose + Br2 water (II) Glucose pentacetate
(C) Glucose + acetic anhydride (III) Saccharic acid
(D) Glucose + HNO3 (IV) Hexane

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Penta-acetate of glucose does not react with hydroxylamine.


The reagents with which glucose does not react to give the corresponding tests/products are:

  1. Tollen’s reagent
  2. Schiff’s reagent
  3. HCN
  4. NH2OH
  5. NaHSO3

Choose the correct options from the given below:


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