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Glucose on Reaction with Hi Gives N-hexane. What Does It Suggest About the Structure of Glucose? - Chemistry

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प्रश्न

Glucose on reaction with HI gives n-hexane. What does it suggest about the structure of glucose?

 

 
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उत्तर

The reaction of glucose with HI giving n-hexane suggests that all the six carbon atoms are linked in a straight chain, as shown in the reaction given below:

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2013-2014 (March) Delhi Set 1

व्हिडिओ ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्‍न

Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.


Maltose is a 

(a) Polysaccharide

(b) Disaccharide

(c) Trisaccharide

(d) Monosaccharide


Enlist the properties of glucose that can not be explained on the basis of open chain structure of it


Oxime is formed by treating glucose with ____________.


When glucose reacts with bromine water, the main product is ____________.


Glucose reacts with acetic anhydride to form ______.


Glucose is found to exist in two different α and β crystalline forms. These forms can be obtained by:

(i) The α form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(ii) The β form of glucose is obtained by crystallisation from a concentrated solution of glucose at 303 K.

(iii) The β form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.

(iv) The α form is obtained by crystallisation from hot and saturated aqueous solution at 371 K.


Reduction of glucose by HI suggest that ____________.


The α-D glucose and β-D glucose differ from each other due to difference in carbon atom with respect to its ____________.


Consider the following reactions:

(i) \[\ce{Glucose + R-OH ->[Conc. HNO3] [A] ->[X eq of][(CH3CO)2O] Acetyl derivative}\]

(ii) \[\ce{Glucose ->[Ni/H2] [A] ->[Y eq of][(CH3CO)2O] Acetyl derivative}\]

(iii) \[\ce{Glucose ->[Z eq of][(CH3CO)2O] Acetyl derivative}\]

'X, 'Y' and 'Z' in these reactions are respectively:


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