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Question
Glucose on reaction with HI gives n-hexane. What does it suggest about the structure of glucose?
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Solution
The reaction of glucose with HI giving n-hexane suggests that all the six carbon atoms are linked in a straight chain, as shown in the reaction given below:

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RELATED QUESTIONS
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
Maltose is a
(a) Polysaccharide
(b) Disaccharide
(c) Trisaccharide
(d) Monosaccharide
Oxime is formed by treating glucose with ____________.
The reaction of glucose with red P + HI is called ____________.
Which is the least stable form of glucose?
Which one is correct?
On the basis of which evidences D-glucose was assigned the following structure?
\[\begin{array}{cc}
\ce{CHO}\\
|\phantom{....}\\
\phantom{..}\ce{(CHOH)4}\\
|\phantom{....}\\
\phantom{..}\ce{CH2OH}
\end{array}\]
Account for the following:
There are 5 OH groups in glucose
Match List - I with List - II.
| List I | List II | ||
| (A) | Glucose + HI | (I) | Gluconic acid |
| (B) | Glucose + Br2 water | (II) | Glucose pentacetate |
| (C) | Glucose + acetic anhydride | (III) | Saccharic acid |
| (D) | Glucose + HNO3 | (IV) | Hexane |
Choose the correct answer from the options given below:
When D-glucose reacts with HI, it forms ______.
