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Question
Answer the following question.
What is the basic structural difference between glucose and fructose?
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Solution
Both Glucose and Fructose are hexose sugars with six carbon atoms but Glucose is an aldohexose and fructose is ketohexose which means the functional group present in glucose is an aldehyde and the functional group in fructose is a ketone.
\[\begin{array}{cc}
\phantom{..}\ce{O}\phantom{..}\ce{H}\phantom{.}\ce{OH}\phantom{.}\ce{OH}\phantom{}\\
\phantom{}||\phantom{...}|\phantom{...}|\phantom{...}|\phantom{.}\\
\ce{CH2OH-C-C-C-C-CH2OH}\\
\phantom{....}|\phantom{...}|\phantom{...}|\phantom{}\\
\phantom{....}\ce{HO}\phantom{..}\ce{H}\phantom{..}\ce{H}\phantom{..}\\
\text{D-fructose}
\end{array}\]
\[\begin{array}{cc}
\phantom{}\ce{OH}\phantom{..}\ce{H}\phantom{.}\ce{OH}\phantom{.}\ce{OH}\phantom{....}\\
\phantom{.}|\phantom{...}|\phantom{...}|\phantom{...}|\phantom{....}\\
\ce{CHO-C-C-C-C-CH2OH}\\
\phantom{}|\phantom{...}|\phantom{...}|\phantom{...}|\phantom{...}\\
\phantom{}\ce{H}\phantom{.}\ce{HO}\phantom{.}\ce{H}\phantom{..}\ce{H}\phantom{..}\\
\text{D-glucose}
\end{array}\]
RELATED QUESTIONS
Enlist the properties of glucose that can not be explained on the basis of open chain structure of it
Write the product when D-glucose reacts with conc. HNO3.
Glucose on reaction with HI gives n-hexane. What does it suggest about the structure of glucose?
Write the reactions involved when D-glucose is treated with the following reagent:
H2N-OH
Which one of the following compounds is different from the rest?
Which of the following properties of glucose cannot be explained by its open chain structure?
(i) Glucose does not form hydrogen sulphite with NaHSO3.
(ii) On oxidation with HNO3 glucose gives saccharic acid.
(iii) Glucose is found to exist in two different crystalline forms which are named as α and β.
In the following reaction, identify A and B:
\[\begin{array}{cc}
\ce{C6H12O6 ->[Acetic anhydride] A}\\
\downarrow \text{Conc. nitric acid}\phantom{...}\\
\ce{B}\phantom{.................}\end{array}\]
How will you distinguish 1° and 2° hydroxyl groups present in glucose? Explain with reactions.
Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction?
The reagents with which glucose does not react to give the corresponding tests/products are:
- Tollen’s reagent
- Schiff’s reagent
- HCN
- NH2OH
- NaHSO3
Choose the correct options from the given below:
