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Write the isomers of the compound having the formula C4H9Br. - Chemistry

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प्रश्न

Write the isomers of the compound having the formula C4H9Br.

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एक पंक्ति में उत्तर
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उत्तर

C4H9Br is a saturated compound because its parent hydrocarbon is C4H10. Its isomers are as follows –

(i) \[\ce{\underset{1-Bromobutane}{CH3 - CH2 - CH2 - CH2 - Br}}\]

(ii) \[\begin{array}{cc}
\phantom{.......}\ce{Br}\\
\phantom{.....}|\\
\ce{\underset{2-Bromobutane}{CH3-CH2-CH-CH3}}
\end{array}\]

(iii) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{\underset{1-Bromo-2-Methylpropane}{CH3-CH-CH2Br}}
\end{array}\]

(iv) \[\begin{array}{cc}
\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - Br}\phantom{.....}\\
|\phantom{...}\\
\phantom{.}\ce{\underset{2-Bromo-2-Methylpropane}{CH3}}
\end{array}\]

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अध्याय 6: Haloalkanes and Haloarenes - Exercises [पृष्ठ १८९]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 6 Haloalkanes and Haloarenes
Exercises | Q 6.6 | पृष्ठ १८९

संबंधित प्रश्न

Write the major products(s) in the following:


In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction?


In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction?


Write the structure of the major organic product in the following reaction:

\[\ce{CH3CH(Br)CH2CH3 + NaOH ->[water]}\]


Out of C6H5CH2Cl and C6H5CHClC6H5, which is more easily hydrolysed by aqueous KOH.


What happens when methyl chloride is treated with KCN?


Which compound in the following pair reacts faster in SN2 reaction with OH?

  1. CH3Br or CH3
  2. CH3Cl, (CH3)3CCl

Which of the following is an example of SN2 reaction?


SN2 mechanism proceeds through intervention of ____________.


Which among MeX, RCH2X, R2CHX and R3CX is most reactive towards SN2 reaction?


Which of the following is an optically active compound?


Racemic compound has ____________.


Which of the following alkyl halides will undergo SN1 reaction most readily?


Read the passage given below and answer the following question:

Nucleophilic substitution reaction of haloalkane can be conducted according to both SN1 and SN2 mechanisms. However, which mechanism it is based on is related to such factors as the structure of haloalkane, and properties of leaving group, nucleophilic reagent and solvent.

Influences of halogen: No matter which mechanism the nucleophilic substitution reaction is based on, the leaving group always leave the central carbon atom with electron pair. This is just the opposite of the situation that nucleophilic reagent attacks the central carbon atom with electron pair. Therefore, the weaker the alkalinity of leaving group is, the more stable the anion formed is and it will be more easier for the leaving group to leave the central carbon atom; that is to say, the reactant is more easier to be substituted. The alkalinity order of halogen ion is I < Br < Cl < F and the order of their leaving tendency should be I > Br > Cl > F. Therefore, in four halides with the same alkyl and different halogens, the order of substitution reaction rate is RI > RBr > RCl > RF. In addition, if the leaving group is very easy to leave, many carbocation intermediates are generated in the reaction and the reaction is based on SN1 mechanism. If the leaving group is not easy to leave, the reaction is based on SN2 a mechanism.

Influences of solvent polarity: In SN1 reaction, the polarity of the system increases from the reactant to the transition state, because polar solvent has a greater stabilizing effect on the transition state than the reactant, thereby reduce activation energy and accelerate the reaction. In SN2 reaction, the polarity of the system generally does not change from the reactant to the transition state and only charge dispersion occurs. At this time, polar solvent has a great stabilizing effect on Nu than the transition state, thereby increasing activation energy and slow down the reaction rate. For example, the decomposition rate (SN1) of tertiary chlorobutane in 25℃ water (dielectric constant 79) is 300000 times faster than in ethanol (dielectric constant 24). The reaction rate (SN2) of 2-bromopropane and NaOH in ethanol containing 40% water is twice slower than in absolute ethanol. In a word, the level of solvent polarity has influence on both SN1 and SN2 reactions, but with different results. Generally speaking, weak polar solvent is favorable for SN2 reaction, while strong polar solvent is favorable for SN1 reaction, because only under the action of polar solvent can halogenated hydrocarbon dissociate into carbocation and halogen ion and solvents with a strong polarity is favorable for solvation of carbocation, increasing its stability. Generally speaking, the substitution reaction of tertiary haloalkane is based on SN1 mechanism in solvents with a strong polarity (for example, ethanol containing water).

SN1 reaction will be fastest in which of the following solvents?


Which of the compounds will react faster in SN1 reaction with the OH ion?

\[\ce{CH3-CH2-Cl}\] or \[\ce{C6H5-CH2-Cl}\]


Chlorination of alkanes is an example of


Which one is the correct order of nucleophilic strength (pKa) of following nucleophiles?


Which of the following compounds will show retention in configuration on nucleophile substitution by OH ion?


Assertion (A) : Nucleophilic substitution of iodoethane is easier than chloroethane.

Reason (R) : Bond enthalpy of C-I bond is less than that of C-Cl bond.


Convert bromoethane to propanamine.


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