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प्रश्न
Assertion (A) : Nucleophilic substitution of iodoethane is easier than chloroethane.
Reason (R) : Bond enthalpy of C-I bond is less than that of C-Cl bond.
विकल्प
Both (A) and (R) are true and (R) is the correct explanation of (A).
Both (A) and (R) are true, but (R) is not the correct explanation of (A).
(A) is true, but (R) is false.
(A) is false, but (R) is true.
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उत्तर
Both (A) and (R) are true and (R) is the correct explanation of (A).
Explanation:
Iodine is a better leaving group than chlorine because of its larger size, it will be released at a higher rate in the presence of an incoming nucleophile.
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संबंधित प्रश्न
Which compound in the following pair will react faster in SN2 reaction with OH−?
(CH3)3CCl or CH3Cl
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH(Br)CH2CH3 + NaOH ->[water]}\]
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
1-Bromobutane, 1-Bromo-2, 2-dimethylpropane, 1-Bromo-2-methylbutane, 1-Bromo-3-methylbutane
Answer the following question.
Write one stereochemical difference between SN1 and SN2 reactions.
Arrange the following organic compounds in descending order of their reactivity towards SN1 reaction.
C6H5CH2Br, C6H5CH(C6H5)Br, C6H5CH(CH3)Br, C6H5C(CH3)(C6H5)Br
Which one is the correct order of nucleophilic strength (pKa) of following nucleophiles?
CCl4 is insoluble in water because:-
The number of chiral alcohol (s) with molecular formula C4H10O is ______.
Discuss SN2 mechanism of methyl bromide using aqueous KOH.
