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प्रश्न
Write the isomers of the compound having the formula C4H9Br.
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उत्तर
C4H9Br is a saturated compound because its parent hydrocarbon is C4H10. Its isomers are as follows –
(i) \[\ce{\underset{1-Bromobutane}{CH3 - CH2 - CH2 - CH2 - Br}}\]
(ii) \[\begin{array}{cc}
\phantom{.......}\ce{Br}\\
\phantom{.....}|\\
\ce{\underset{2-Bromobutane}{CH3-CH2-CH-CH3}}
\end{array}\]
(iii) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{\underset{1-Bromo-2-Methylpropane}{CH3-CH-CH2Br}}
\end{array}\]
(iv) \[\begin{array}{cc}
\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - Br}\phantom{.....}\\
|\phantom{...}\\
\phantom{.}\ce{\underset{2-Bromo-2-Methylpropane}{CH3}}
\end{array}\]
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संबंधित प्रश्न
Give reasons for the following:
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Which would undergo SN2 reaction faster in the following pair and why ?

Which would undergo SN2 reaction faster in the following pair and why ?
CH3 – CH2 – Br and CH3 – CH2 – I
Answer the following question.
Write one stereochemical difference between SN1 and SN2 reactions.
Which of the following is a primary halide?
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The process of separation of a racemic modification into d and l-enantiomers is called ____________.
Racemic compound has ____________.
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Elimination reactions (especially β-elimination) are as common as the nucleophilic substitution reaction in case of alkyl halides. Specify the reagents used in both cases.
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The decreasing order of reactivity of the following compounds towards nucleophilic substitution (SN2) is ______.
Retention of configuration is observed in ______.
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
|
Nucleophilic Substitution: Influences of solvent polarity: The reaction rate (SN2) of 2-bromopropane and NaOH in ethanol containing 40% water is twice slower than in absolute ethanol. Hence the level of solvent polarity has an influence on both SN1 and SN2 reactions but with different results. Generally speaking, a weak polar solvent is favourable for SN2 reaction, while a strong polar solvent is favourable for SN1. Generally speaking, the substitution reaction of tertiary haloalkane is based on SN1 mechanism in solvents with a strong polarity (for example ethanol containing water). |
Answer the following questions:
(a) Why racemisation occurs in SN1? (1)
(b) Why is ethanol less polar than water? (1)
(c) Which one of, the following in each pair is more reactive towards SN2 reaction? (2)
(i) CH3 – CH2 – I or CH3CH2 – Cl
(ii)

OR
(c) Arrange the following in the increasing order of their reactivity towards SN1 reactions: (2)
(i) 2-Bromo-2-methylbutane, 1-Bromo-pentane, 2-Bromo-pentane
(ii) 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3- methylbutane
Discuss the mechanism of alkaline hydrolysis of methyl bromide.
Which one of the following chlorohydrocarbons readily undergoes solvolysis?
Which of the following reactions is an example of nucleophilic substitution reaction?




