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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Which compound in the following pair will react faster in SN2 reaction with OH−? CH3Br or CH3I

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प्रश्न

Which compound in the following pair will react faster in SN2 reaction with OH?

CH3Br or CH3I

लघु उत्तरीय
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उत्तर

In the SN2 mechanism, the reactivity of halides for the same alkyl group increases in the order. This happens because, as the size increases, the halide ion becomes a better leaving group.

R−F << R−Cl < R−Br < R−I

Therefore, CH3I will react faster than CH3Br in SN2 reactions with OH.

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अध्याय 6: Haloalkanes and Haloarenes - Exercises [पृष्ठ १९०]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 6 Haloalkanes and Haloarenes
Exercises | Q 6.9 (i) | पृष्ठ १९०
नूतन Chemistry [English] Class 12 ISC
अध्याय 6 Haloalkanes and Haloarenes
VERY SHORT ANSWER TYPE QUESTIONS | Q 33. (a) | पृष्ठ ६०९

संबंधित प्रश्न

What are ambident nucleophiles? Explain with an example.


What is the action of the following on ethyl bromide?

silver acetate


In the reaction, \[\ce{R - X + NaOR' -> ROR’ + X}\] ( – ve ion). The main product formed is:


Which of the following is optically inactive?


In the SN1 reaction, racemization takes place. It is due to:


Which of the following is an optically active compound?


The process of separation of a racemic modification into d and l-enantiomers is called ____________.


The increasing order of reactivity towards SN1 mechanism is:

(I) \[\begin{array}{cc}
\ce{CH3-CH-CH2-CH3}\\
|\phantom{........}\\
\ce{CH3}\phantom{.....}
\end{array}\]

(II) CH3CH2CH2Cl

(III) P–CH3O–C6H4–CH2Cl


Assertion: KCN reacts with methyl chloride to give methyl isocyanide.

Reason: CN is an ambident nucleophile.


A primary alkyl halide would prefer to undergo ______.


Which of the following is the definition of chirality?


Give reason for the following:

The product formed during SN1 reaction is a racemic mixture.


Optical activity of an enantiomeric mixture is +12.6° and the specific rotation of (+) isomer is +30°. The optical purity is ______ %.


Assertion (A) : Nucleophilic substitution of iodoethane is easier than chloroethane.

Reason (R) : Bond enthalpy of C-I bond is less than that of C-Cl bond.


Convert bromoethane to propanamine.


Give the mechanism of the following reaction:

\[\ce{CH3CH2OH ->[H2SO4][413 K] CH3CH2-O-CH2CH3 + H2O}\]


Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.

\[\begin{array}{cc}\ce{CH3CH2CHCH3}\\
\phantom{.....}|\\
\phantom{......}\ce{Br}\\
\end{array}\] or \[\begin{array}{cc}\phantom{.......}\ce{CH3}\\
\phantom{...}|\\
\ce{H3C - C - Br}\\
\phantom{...}|\\
\phantom{.......}\ce{CH3}\\
\end{array}\]


The correct order of increasing reactivity of

C-X bond towards nucleophile in the following compounds is:


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