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प्रश्न
How are amines classified?
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उत्तर
Classification of Amines:
i. Amines are classified as primary (1°), secondary (2°), and tertiary (3°) amines.
ii. Their structures are obtained in a simple way by replacing one, two, or three hydrogen atoms of NH3 molecule by alkyl/aryl groups.
iii. Secondary and tertiary amines are further classified as simple or symmetrical amines and mixed or unsymmetrical amines.
iv. When all the alkyl or aryl groups on nitrogen are the same, it is a simple amine. If these groups are different, then the amine is a mixed amine.
v. Amines are also divided into two major classes, namely, aliphatic and aromatic amines on the basis of the nature of the groups attached to the nitrogen atom.
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संबंधित प्रश्न
Classify the following amine as primary, secondary or tertiary:
(C2H5)2NH
Give reasons for the following:
CH3NH2 is more basis than C6H5NH2.
Choose the most correct option.
The hybridisation of nitrogen in primary amine is ____________.
Choose the most correct option.
Which type of amine does produce N2 when treated with HNO2?
Choose the most correct option.
Carbylamine test is given by ____________.
Choose the most correct option.
Identify ‘B’ in the following reactions
\[\ce{CH3 - C ≡ N ->[Na/C2H5OH] A ->[NaNO2/dilHCl]B}\]
What are amines?
Write the number of moles of ethanoyl chloride required for complete acylation of N, N-dimethylaniline.
What is the action of nitrous acid on the following compounds?
Isopropyl amine
Which of the following amines is most basic in nature in aqueous phase?
Assertion: Acetamide on reaction with KOH and bromine gives acetic acid.
Reason: Bromine catalyses hydrolysis of acetamide.
\[\ce{Aniline + benzoylchloride ->[NaOH] C6H5 - NH - COC6H5}\] this reaction is known as ____________.
\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2/HCl][273 K] B ->[H2O][283 K] C}\] ‘C’ is:
How will you convert nitrobenzene into m-nitro aniline?
Write a short note on the following.
Ammonolysis
Write a short note on the following:
Gabriel phthalimide synthesis
Write a short note on the following.
Schotten-Baumann reaction
Write a short note on the following.
Carbylamine reaction
How will you distinguish between primary secondary and tertiary aliphatic amines?
Account for the following.
pKb of aniline is more than that of methylamine.
Account for the following.
Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Account for the following.
Ethylamine is soluble in water whereas aniline is not.
Account for the following.
Although amino group is o- and p-directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
Arrange the following:
In increasing order of solubility in water:
C6H5NH2, (C2H5)2NH, C2H5NH2
Arrange the following.
In decreasing order of the pKb values C2H5NH2, C6H5NHCH3, (C2H)2NH and CH3NH2.
Arrange the following.
In decreasing order of basic strength
How will you prepare propan-1-amine from propanamide?
How will you prepare propan-1-amine from 1-nitropropane?
Identify A, B and C.
\[\ce{CH3 - NO2 ->[LiAlH4] A ->[2CH3CH2Br] B ->[H2SO4] C}\]
How will you convert diethylamine into N-nitrosodiethylamine?
(C2H5)2CHNH2. The following amine can be classified as:
The following amine can be classified as (C2H5)2NH:
The main product is formed by treating an alkyl or benzyl halide with excess ammonia ____________.
Arrange the following in the increasing order of their basic strength:
C2H5NH2, C6H5NH2, (C2H5)2NH
Complete the following reaction.
The amine formed from an amide by mean of bromine and alkali has how many number of carbon atoms?
Classify the following amine as primary, secondary or tertiary:
Which among the following is the strongest Bronsted base?
Among the following, which is the strongest base?
Write short notes on the following
Ammonolysis
Write a short note on the following.
Ammonolysis
Name the distinguishing test for differentiating 1° amine from 2° and 3° amine.
Write a short note on the following
Ammonolysis
Account for the following:
Aniline does not undergo Friedel-Crafts reaction.
Write short note on the following.
Ammonolysis
Write short note on the following:
Ammonolysis
Write a short note on the following.
Ammonolysis
Write a short note on the following.
Ammonolysis
