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Questions
Write the two applications of Henry’s law.
Mention some important applications of Henry’s law.
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Solution
- To increase the solubility of CO2 in soft drinks and soda water, the bottle is sealed under high pressure.
- Aquatic species feel uncomfortable in hot water.
- Scuba divers must cope with high concentrations of dissolved gases while breathing high-pressure air underwater. Increased pressure increases the solubility of atmospheric gases in blood. When the divers come towards the surface, the pressure gradually decreases. This releases dissolved gases, leading to the formation of nitrogen bubbles in the blood. This blocks capillaries and causes a medical condition known as the bends, which is painful and life-threatening. To avoid bends and the toxic effects of high concentrations of nitrogen in the blood, the tanks used by scuba divers are filled with air diluted with helium (11.7% helium, 56.2% nitrogen, and 32.1% oxygen).
- At high altitudes, the partial pressure of oxygen is less than that at the ground level. This leads to low oxygen concentrations in the blood and tissues of people living at high altitudes or of climbers. Low blood oxygen causes climbers to become weak and unable to think clearly, symptoms of a condition known as anoxia.
- The way that oxygen reaches tissues is explained by Henry’s law. Because of the high partial pressure of oxygen in the lungs, when air is inhaled, it combines with the blood’s haemoglobin to generate oxyhaemoglobin. In tissues, the partial pressure of oxygen is low. As a result, oxyhaemoglobin releases oxygen, which the cells use.
RELATED QUESTIONS
What is the effect of temperature on solubility of a gas in a liquid?
Why do gases always tend to be less soluble in liquids as the temperature is raised?
Henry’s law constant for CO2 in water is 1.67 × 108 Pa at 298 K. Calculate the quantity of CO2 in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm Hg. Calculate the solubility of methane in benzene at 298 K under 760 mm Hg.
Which mixture is used for respiration by deep sea divers?
(A) He + O2
(B) Ne + O2
(C) Ar + O2
(D) Kr + O2
State Henry's Law. What is the effect of temperature on the solubility of a gas in a liquid?
A solution is prepared by dissolving 9.25 g of non-volatile solute in 450 mL of water. It has an osmotic pressure of 350 mm of Hg at 27°C. Assuming the solute is non-electrolyte, determine its molecular mass. (R = 0.0821 Lit-atm K−1 mol−1)
According to Henry’s law, the amount of gas that will dissolve in blood plasma or any other liquid is determined by which of these factors?
Low concentration of oxygen in the blood and tissues of people living at high altitude is due to ______.
The value of Henry's constant KH is ______.
Which of the following factor(s) affect the solubility of a gaseous solute in the fixed volume of liquid solvent?
(a) nature of solute
(b) temperature
(c) pressure
(i) (a) and (c) at constant T
(ii) (a) and (b) at constant P
(iii) (b) and (c) only
(iv) (c) only
Solubility of gases in liquids decreases with rise in temperature because dissolution is an ______.
KH value for \[\ce{Ar(g)}\], \[\ce{CO2(g)}\], \[\ce{HCHO (g)}\] and \[\ce{CH4(g)}\] are 40.39, 1.67, 1.83 × 10–5 and 0.413 respectively. Arrange these gases in the order of their increasing solubility.
What is the significance of Henry’s Law constant KH?
Match the items given in Column I with the type of solutions given in Column II.
| Column I | Column II |
| (i) Soda water | (a) A solution of gas in solid |
| (ii) Sugar solution | (b) A solution of gas in gas |
| (iii) German silver | (c) A solution of solid in liquid |
| (iv) Air | (d) A solution of solid in solid |
| (v) Hydrogen gas in palladium | (e) A solution of gas in liquid |
| (f) A solution of liquid in solid |
State Henry’s law and explain why are the tanks used by scuba divers filled with air diluted with helium (11.7% helium, 56.2% nitrogen and 32.1% oxygen)?
Henry's constant (in k bar) for four gases α, β, γ and δ in water at 298 K is given below:
| α | β | γ | δ | |
| KH | 50 | 2 | 2 × 10-5 | 0.5 |
(density of water = 103 kg m-3 at 298 K)
This table implies that:
Identify that the following compound is insoluble, partially soluble and highly soluble in water.
phenol
Assertion (A): Helium is used to dilute oxygen in diving apparatus.
Reason (R): Helium has high solubility in O.
In the light of the above statements, choose the correct answer from the options given below:
