Advertisements
Advertisements
Question
How does solubility of a gas in water varies with the temperature?
Advertisements
Solution
According to Charle’s law, volume of a given mass of a gas increases with increase in temperature.
Therefore, the volume of a given mass of dissolved gas increases with temperature, making it impossible for the solvent to accommodate the gaseous solute, which then forms gas bubbles.
Hence, the solubility of a gas in a liquid decreases with increasing temperature.
APPEARS IN
RELATED QUESTIONS
Why do gases always tend to be less soluble in liquids as the temperature is raised?
H2S, a toxic gas with rotten egg like smell, is used for the qualitative analysis. If the solubility of H2S in water at STP is 0.195 m, calculate Henry’s law constant.
Which mixture is used for respiration by deep sea divers?
(A) He + O2
(B) Ne + O2
(C) Ar + O2
(D) Kr + O2
Give reasons for the following :
Aquatic animals are more comfortable in the cold water than in warm water.
The solubility product (Ksp) of BaSO4 is 1.5 X 10-9.Calculate the solubility of barium sulphate in pure water and in 0.1 M BaCl2.
A solution is prepared by dissolving 9.25 g of non-volatile solute in 450 mL of water. It has an osmotic pressure of 350 mm of Hg at 27°C. Assuming the solute is non-electrolyte, determine its molecular mass. (R = 0.0821 Lit-atm K−1 mol−1)
Write the name of gas released when Cu is added to dilute HNO3
Write the name of gas released when Cu is added to the conc. HNO3
Which law shows relation between pressure and solubility of a gas in solvent?
The statement “If 0.003 moles of a gas are dissolved in 900 g of water under a pressure of 1 atmosphere, 0.006 moles will be dissolved under a pressure of 2 atmospheres”, illustrates.
According to Henry’s law, the amount of gas that will dissolve in blood plasma or any other liquid is determined by which of these factors?
The value of Henry's constant KH is ______.
KH value for \[\ce{Ar(g)}\], \[\ce{CO2(g)}\], \[\ce{HCHO (g)}\] and \[\ce{CH4(g)}\] are 40.39, 1.67, 1.83 × 10–5 and 0.413 respectively. Arrange these gases in the order of their increasing solubility.
Explain the solubility rule “like dissolves like” in terms of intermolecular forces that exist in solutions.
What is the significance of Henry’s Law constant KH?
Match the items given in Column I with the type of solutions given in Column II.
| Column I | Column II |
| (i) Soda water | (a) A solution of gas in solid |
| (ii) Sugar solution | (b) A solution of gas in gas |
| (iii) German silver | (c) A solution of solid in liquid |
| (iv) Air | (d) A solution of solid in solid |
| (v) Hydrogen gas in palladium | (e) A solution of gas in liquid |
| (f) A solution of liquid in solid |
The solubility of a gas in water depends on ______
Explain the following phenomena with the help of Henry’s law.
Feeling of weakness and discomfort in breathing at high altitude.
Assume that argon exerts a partial pressure of 6 bar. Calculate the solubility of argon gas in water. (Given Henry’s law constant for argon dissolved in water, KH = 40 k bar)
If O2 gas is bubbled through water at 303 K, the number of millimoles of O2 gas that dissolve in 1 litre of water is ______. (Nearest integer)
(Given: Henry's Law constant for O2 at 303 K is 46.82 k bar and partial pressure of O2 = 0.920 bar)
(Assume solubility of O2 in water is too small, nearly negligible)
In which of the following solvents, the \[\ce{C4H8NH3+X–}\] is soluble?
Write the two applications of Henry’s law.
Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble in water?
- phenol
- toluene
- formic acid
- ethylene glycol
- chloroform
- pentanol
Assertion (A): Helium is used to dilute oxygen in diving apparatus.
Reason (R): Helium has high solubility in O.
In the light of the above statements, choose the correct answer from the options given below:
