English

Observe the following and answer the question given below. Can it react by SN1 mechanism? Justify your answer. - Chemistry

Advertisements
Advertisements

Question

Observe the following and answer the question given below.

Can it react by SN1 mechanism? Justify your answer.

Short/Brief Note
Advertisements

Solution

It will not react by SN1 mechanism. The bond between sp2 hybridized carbon atom and halogen is a strong bond. Also, the electrons of the –X atom are in conjugation with the π bond. Thus, C – X bond acquires a double bond character. Thus, when nucleophile approaches the sp2 carbon, it gets repelled by the π-electrons of the double bond.

shaalaa.com
Chemical Properties
  Is there an error in this question or solution?
Chapter 10: Halogen Derivatives - Exercises [Page 233]

APPEARS IN

Balbharati Chemistry [English] Standard 12 Maharashtra State Board
Chapter 10 Halogen Derivatives
Exercises | Q 7. iii. c. | Page 233

RELATED QUESTIONS

from the following pair would undergo SN2 faster from the other?

a. CH3CH2CH2I      b. CH3CH2CH2Cl


Complete the following reaction giving major products.

\[\begin{array}{cc}\ce{CH3 - CH = CH3 ->[Red P/Br2] A ->[Ag2O/H2O]B}\\|\phantom{.........................}\\
\ce{OH\phantom{.......................}}\end{array}\]


Name the reagent used to bring about the following conversion.

Ethyl bromide to ethyl isocyanide


Arrange the following in the increasing order of boiling points.

  1. 1-Bromopropane
  2. 2- Bromopropane
  3. 1- Bromobutane
  4. 1-Bromo-2-methylpropane

Give reasons:

Haloarenes are less reactive than haloalkanes.


Distinguish between SN1 and SN2 mechanism of substitution reaction.


Convert the following:

Ethanol to propane nitrile


Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.

\[\ce{Isopropyl alcohol ->[\triangle][PBr3] A ->[][NH3 excess] B}\]


Observe the following and answer the question given below.

Name the type of halogen derivative.


Major product of the following reaction is _______________

\[\ce{CH3-CH2-Mg-Br + NH3 ->?}\]


Nucleophilic substitution reaction of 2, 4-dinitrochlorobenzene is faster than p-nitrochlorobenzene. Give reason.


Explain the factors affecting SN1 and SN2 mechanism.


Which of the following is least reactive towards nucleophilic addition?


Nitroalkanes are obtained in laboratory from primary or secondary alkyl halides by the action of ______.


The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:

\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]

\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]

The order of the reaction with respect to NO2(g)


How many metameric ethers are represented by the molecular formula C4H10O?


Identify major product 'B' in the following reaction.

\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]


What is the major product obtained in the sulphonation of chlorobenzene with concentrated sulphuric acid?


Convert the following.

p-Nitrochlorobenzene to p-nitrophenol


The order of reactivities of the following alkyl halides for an SN2 reaction is ______.


Explain the dehydrohalogenation reaction of 2-chlorobutane.


Complete the following reactions giving a major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Complete the reaction:

\[\ce{CH3CH2Cl ->[AgCN][alc.\Delta]}\] ?


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Give a reason for the following:

Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×