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Observe the following and answer the question given below. Can it react by SN1 mechanism? Justify your answer.

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Question

Observe the following and answer the question given below.

Can it react by SN1 mechanism? Justify your answer.

Short/Brief Note
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Solution

It will not react by SN1 mechanism. The bond between sp2 hybridized carbon atom and halogen is a strong bond. Also, the electrons of the –X atom are in conjugation with the π bond. Thus, C – X bond acquires a double bond character. Thus, when nucleophile approaches the sp2 carbon, it gets repelled by the π-electrons of the double bond.

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Chapter 10: Halogen Derivatives - Exercises [Page 233]

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Balbharati Chemistry [English] Standard 12 Maharashtra State Board
Chapter 10 Halogen Derivatives
Exercises | Q 7. iii. c. | Page 233

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