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प्रश्न
Observe the following and answer the question given below.
Can it react by SN1 mechanism? Justify your answer.
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उत्तर
It will not react by SN1 mechanism. The bond between sp2 hybridized carbon atom and halogen is a strong bond. Also, the electrons of the –X atom are in conjugation with the π bond. Thus, C – X bond acquires a double bond character. Thus, when nucleophile approaches the sp2 carbon, it gets repelled by the π-electrons of the double bond.
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संबंधित प्रश्न
from the following pair would undergo SN2 faster from the other?
from the following pair would undergo SN2 faster from the other?
a. CH3CH2CH2I b. CH3CH2CH2Cl
Name the reagent used to bring about the following conversion.
Bromoethane to ethoxyethane
Name the reagent used to bring about the following conversion.
Chlorobenzene to biphenyl
Arrange the following in the increasing order of boiling points.
- 1-Bromopropane
- 2- Bromopropane
- 1- Bromobutane
- 1-Bromo-2-methylpropane
Convert the following:
Benzyl alcohol to benzyl cyanide
Convert the following:
2-Chloropropane to propan-1-ol
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Observe the following and answer the question given below.
Name the type of halogen derivative.
Observe the following and answer the question given below.
Comment on the bond length of C–X bond in it.
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Explain primary benzylic halide shows higher reactivity by SN1 mechanism than other primary alkyl halide.
Explain aqueous alkaline hydrolysis of tert. butyl bromide.
The least reactive towards nucleophilic addition reactions is ____________.
Nitroalkanes are obtained in laboratory from primary or secondary alkyl halides by the action of ______.
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\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]
\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]
The order of the reaction with respect to NO2(g)
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p-Nitrochlorobenzene to p-nitrophenol
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With which halogen the reactions, of alkanes are explosive?
Observe the following and answer the question given below:
Comment on the bond length of C-X bond in it.
Complete the following reaction sequences by writing the structural formulae of the organic compounds 'A', 'B' and 'C'.
\[\ce{2-Bromobutan ->[alc. KOH] A ->[][Br2] B ->[][NANH2] C}\]
Complete the reaction:
\[\ce{CH3CH2Cl ->[AgCN][alc.\Delta]}\] ?
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
