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Observe the following and answer the question given below. Can it react by SN1 mechanism? Justify your answer.

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प्रश्न

Observe the following and answer the question given below.

Can it react by SN1 mechanism? Justify your answer.

टीपा लिहा
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उत्तर

It will not react by SN1 mechanism. The bond between sp2 hybridized carbon atom and halogen is a strong bond. Also, the electrons of the –X atom are in conjugation with the π bond. Thus, C – X bond acquires a double bond character. Thus, when nucleophile approaches the sp2 carbon, it gets repelled by the π-electrons of the double bond.

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पाठ 10: Halogen Derivatives - Exercises [पृष्ठ २३३]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 10 Halogen Derivatives
Exercises | Q 7. iii. c. | पृष्ठ २३३

संबंधित प्रश्‍न

Name the reagent used to bring about the following conversion.

1-Chloropropane to 1-nitropropane


Distinguish between SN1 and SN2 mechanism of substitution reaction.


Convert the following:

Propene to propan-1-ol


Convert the following:

2-Chloropropane to propan-1-ol


Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.

\[\ce{Isopropyl alcohol ->[\triangle][PBr3] A ->[][NH3 excess] B}\]


Observe the following and answer the question given below.

Comment on the bond length of C–X bond in it.


The following will react faster by SN1 mechanism


Nucleophilic substitution reaction of 2, 4-dinitrochlorobenzene is faster than p-nitrochlorobenzene. Give reason.


Explain aqueous alkaline hydrolysis of tert. butyl bromide.


In alkaline hydrolysis of tertiary butyl bromide, ____________.


Which of the following is least reactive towards nucleophilic addition?


Dehydrohalogenation of an alkyl halide is ____________.


Nitroalkanes are obtained in laboratory from primary or secondary alkyl halides by the action of ______.


The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:

\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]

\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]

The order of the reaction with respect to NO2(g)


How many metameric ethers are represented by the molecular formula C4H10O?


Which of the following carbocation is the most stable?


Identify major product 'B' in the following reaction.

\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]


What is the major product obtained in the sulphonation of chlorobenzene with concentrated sulphuric acid?


The major product formed when 2-bromobutane is treated with alcoholic KOH is ______.


Explain the dehydrohalogenation reaction of 2-chlorobutane.


Complete the following reaction giving a major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Observe the following and answer the questions given below:

Name the type of halogen derivative.


Complete the following reaction, giving a major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/ dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]


Which of the following reagent is used for conversion of alkyl halide into nitrile?


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