Advertisements
Advertisements
प्रश्न
Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.
\[\ce{Isopropyl alcohol ->[\triangle][PBr3] A ->[][NH3 excess] B}\]
Advertisements
उत्तर
\[\begin{array}{cc}
\ce{H3C - CH - OH ->[\triangle][PBr3] H3C - CH - Br ->[NH3, Excess]H3C - CH - NH2}\\
|\phantom{......................}|\phantom{..........................}|\phantom{..}\\
\phantom{.......}\ce{\underset{\text{Isopropyl alcohol}}{CH3}\phantom{.......}}
\ce{\underset{\text{Isopropyl bromide (A)}}{CH3}\phantom{.........}\phantom{}}
\ce{\underset{\text{Propan-2-amine (B)}}{CH3}}
\end{array}\]
APPEARS IN
संबंधित प्रश्न
from the following pair would undergo SN2 faster from the other?
from the following pair would undergo SN2 faster from the other?
a. CH3CH2CH2I b. CH3CH2CH2Cl
Complete the following reaction giving major products.
\[\ce{CH3 - CH = CH2 ->[HBr][peroxide] A ->[alc. KOH] B}\]
Complete the following reaction giving major products.
\[\begin{array}{cc}\ce{CH3 - CH = CH3 ->[Red P/Br2] A ->[Ag2O/H2O]B}\\|\phantom{.........................}\\
\ce{OH\phantom{.......................}}\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}\ce{CH3\phantom{................}}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3\phantom{................}}
\end{array}\]
Name the reagent used to bring about the following conversion.
Bromoethane to ethoxyethane
Arrange the following in the increasing order of boiling points.
- 1-Bromopropane
- 2- Bromopropane
- 1- Bromobutane
- 1-Bromo-2-methylpropane
Distinguish between SN1 and SN2 mechanism of substitution reaction.
Convert the following:
Benzyl alcohol to benzyl cyanide
Convert the following:
tert-Butyl bromide to isobutyl bromide
Observe the following and answer the question given below.
Comment on the bond length of C–X bond in it.
Observe the following and answer the question given below.
Can it react by SN1 mechanism? Justify your answer.
Write the correct order of increasing ease of dehydrohalogenation.
\[\ce{\underset{\text{(I)}}{CH3 - CH2 - CH2 - Cl}}\]
\[\ce{\underset{\text{(II)}}{CH3 - CH(Cl) - CH3}}\]
\[\begin{array}{cc}
\ce{CH3}\\
|\\
\ce{CH3-C-Cl}\phantom{...}\\
|\\
\ce{CH3}\\
\ce{(III)}
\end{array}\]
Explain aqueous alkaline hydrolysis of tert. butyl bromide.
Which of the following is least reactive towards SN1 reactions?
The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:
\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]
\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]
The order of the reaction with respect to NO2(g)
The SN2 reaction of a compound containing an asymmetric carbon atom always gives ____________.
Identify 'B' in the following reaction.
\[\ce{2-Bromobutane ->[KOH alc.][\Delta] A ->[HI] B}\]
Convert the following.
p-Nitrochlorobenzene to p-nitrophenol
With which halogen the reactions, of alkanes are explosive?
The compound that reacts the fastest with sodium methoxide is ______.
Explain the dehydrohalogenation reaction of 2-chlorobutane.
Observe the following and answer the question given below:
Comment on the bond length of C-X bond in it.
Discuss β - elimination reaction.
What is the action of following on ethyl bromide?
alcoholic sodium hydroxide
Identify the chiral molecule from the following.
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Give a reason for the following:
Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]
