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प्रश्न
Distinguish between SN1 and SN2 mechanism of substitution reaction.
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उत्तर
| Factor | SN1 | SN2 |
| Kinetics | 1st order | 2nd order |
| Molecularity | Unimolecular | Bimolecular |
| Number of steps | Two steps | One step |
| Bond making and bond breaking | First the bond in the reactant breaks and then a new bond in the product is formed. | Simultaneous |
| Transition state | Two steps, two transition states | One step, one transition state |
| Direction of attack of nucleophile | Backside attack and frontside attack | Only back side attack |
| Stereochemistry | Racemisation (If the substrate is optically active) | Inversion of configuration (If the substrate is optically active) |
| Type of substrate | Mainly 3° substrates | Mainly 1° substrate |
| Polarity of solvent | Polar protic solvent favorable | Aprotic (non-polar) or solvent with low polarity favourable |
| Intermediate | Intermediate involved | No intermediate |
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संबंधित प्रश्न
from the following pair would undergo SN2 faster from the other?
from the following pair would undergo SN2 faster from the other?
a. CH3CH2CH2I b. CH3CH2CH2Cl
Convert the following:
Propene to propan-1-ol
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\[\ce{2-Bromobutane->[Alc.KOH]A->[][Br2]B->[][NaNH2]C}\]
Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.
\[\ce{Isopropyl alcohol ->[\triangle][PBr3] A ->[][NH3 excess] B}\]
Observe the following and answer the question given below.
Name the type of halogen derivative.
Major product of the following reaction is _______________
\[\ce{CH3-CH2-Mg-Br + NH3 ->?}\]
Write the correct order of increasing ease of dehydrohalogenation.
\[\ce{\underset{\text{(I)}}{CH3 - CH2 - CH2 - Cl}}\]
\[\ce{\underset{\text{(II)}}{CH3 - CH(Cl) - CH3}}\]
\[\begin{array}{cc}
\ce{CH3}\\
|\\
\ce{CH3-C-Cl}\phantom{...}\\
|\\
\ce{CH3}\\
\ce{(III)}
\end{array}\]
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Which one is most reactive towards nucleophilic addition reaction?
What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?
Which of the following is FALSE regarding SN2 reaction mechanism?
The SN2 reaction of a compound containing an asymmetric carbon atom always gives ____________.
Identify major product 'B' in the following reaction.
\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]
Identify 'B' in the following reaction.
\[\ce{2-Bromobutane ->[KOH alc.][\Delta] A ->[HI] B}\]
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With which halogen the reactions, of alkanes are explosive?
Complete the following reaction giving major products.
\[\begin{array}{cc}
\ce{CH3}\phantom{.......}\\
|\phantom{.........}\\
\ce{CH3 - c - CH2 - Cl ->[Na/dry ether]}\\
|\phantom{.........}\\
\ce{CH3}\phantom{.......}
\end{array}\]
Observe the following and answer the questions given below:
Name the type of halogen derivative.
Complete the reaction:
\[\ce{CH3CH2Cl ->[AgCN][alc.\Delta]}\] ?
Identify the chiral molecule from the following.
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{...............}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]
