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Observe the following and answer the question given below. Can it react by SN1 mechanism? Justify your answer. - Chemistry

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प्रश्न

Observe the following and answer the question given below.

Can it react by SN1 mechanism? Justify your answer.

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उत्तर

It will not react by SN1 mechanism. The bond between sp2 hybridized carbon atom and halogen is a strong bond. Also, the electrons of the –X atom are in conjugation with the π bond. Thus, C – X bond acquires a double bond character. Thus, when nucleophile approaches the sp2 carbon, it gets repelled by the π-electrons of the double bond.

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अध्याय 10: Halogen Derivatives - Exercises [पृष्ठ २३३]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 10 Halogen Derivatives
Exercises | Q 7. iii. c. | पृष्ठ २३३

संबंधित प्रश्न

from the following pair would undergo SN2 faster from the other?

a. CH3CH2CH2I      b. CH3CH2CH2Cl


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Name the reagent used to bring about the following conversion.

Ethyl bromide to ethyl isocyanide


Name the reagent used to bring about the following conversion.

Chlorobenzene to biphenyl


Convert the following:

Propene to propan-1-ol


Convert the following:

2-Chloropropane to propan-1-ol


Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.

\[\ce{2-Bromobutane->[Alc.KOH]A->[][Br2]B->[][NaNH2]C}\]


Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.

\[\ce{Isopropyl alcohol ->[\triangle][PBr3] A ->[][NH3 excess] B}\]


Observe the following and answer the question given below.

Name the type of halogen derivative.


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Explain the factors affecting SN1 and SN2 mechanism.


In alkaline hydrolysis of tertiary butyl bromide, ____________.


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Which of the following is least reactive towards nucleophilic addition?


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Nitroalkanes are obtained in laboratory from primary or secondary alkyl halides by the action of ______.


The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:

\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]

\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]

The order of the reaction with respect to NO2(g)


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\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]


Which among the following statements is not correct about SN2 reaction mechanism?


What is the action of following on ethyl bromide?

alcoholic sodium hydroxide


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]


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