हिंदी

Observe the following and answer the question given below. Can it react by SN1 mechanism? Justify your answer.

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प्रश्न

Observe the following and answer the question given below.

Can it react by SN1 mechanism? Justify your answer.

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उत्तर

It will not react by SN1 mechanism. The bond between sp2 hybridized carbon atom and halogen is a strong bond. Also, the electrons of the –X atom are in conjugation with the π bond. Thus, C – X bond acquires a double bond character. Thus, when nucleophile approaches the sp2 carbon, it gets repelled by the π-electrons of the double bond.

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अध्याय 10: Halogen Derivatives - Exercises [पृष्ठ २३३]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 10 Halogen Derivatives
Exercises | Q 7. iii. c. | पृष्ठ २३३

संबंधित प्रश्न

from the following pair would undergo SN2 faster from the other?

  1.    

Arrange the following in the increasing order of boiling points.

  1. 1-Bromopropane
  2. 2- Bromopropane
  3. 1- Bromobutane
  4. 1-Bromo-2-methylpropane

Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.

\[\ce{Isopropyl alcohol ->[\triangle][PBr3] A ->[][NH3 excess] B}\]


Propane nitrile can be prepared by heating ____________


Explain. Aryl halides are less reactive than alkyl halides towards nucleophilic substitution reactions.


Explain primary benzylic halide shows higher reactivity by SN1 mechanism than other primary alkyl halide.


Explain aqueous alkaline hydrolysis of tert. butyl bromide.


In alkaline hydrolysis of tertiary butyl bromide, ____________.


Ethyl bromide undergoes the following reaction:

\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]

Which of the following is a WRONG statement?


Dehydrohalogenation of an alkyl halide is ____________.


What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?


\[\ce{C6H5CH2Cl + KCN(alc) -> X + Y}\]

Compounds X and Y are ____________.


Which of the following is FALSE regarding SN2 reaction mechanism?


What is the major product obtained in the sulphonation of chlorobenzene with concentrated sulphuric acid?


Convert the following.

p-Nitrochlorobenzene to p-nitrophenol


Which of the following statements is incorrect regarding the dehydrohalogenation of alkenes?


The order of reactivity of the given haloalkanes towards nucleophiles is:


Complete the following reactions giving a major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Observe the following and answer the question given below:

Comment on the bond length of C-X bond in it.


Complete the following reaction sequences by writing the structural formulae of the organic compounds 'A', 'B' and 'C'.

\[\ce{2-Bromobutan ->[alc. KOH] A ->[][Br2] B ->[][NANH2] C}\]


Complete the following reactions giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]


Complete the reaction:

\[\ce{CH3CH2Cl ->[AgCN][alc.\Delta]}\] ?


Give a reason for the following:

Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]


Which of the following pair of compounds on heating gives butanenitrile?


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