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From the following pair would undergo SN2 faster from the other?

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प्रश्न

from the following pair would undergo SN2 faster from the other?

  1.    
एक पंक्ति में उत्तर
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उत्तर

Compound (a) will undergo SN2 mechanism faster than (b).

Explanation:

  1. Sincey  is a primary halide it undergoes S2N reaction faster than .
  2. Since iodine is a better leaving group than chloride, 1-iodo propane (CH3CH2CH2I) undergoes S2N reaction faster than l-chloropropane (CH3CH2CH2CI).
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अध्याय 10: Halogen Derivatives - Exercises [पृष्ठ २३२]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 10 Halogen Derivatives
Exercises | Q 2. iv. a. | पृष्ठ २३२

संबंधित प्रश्न

from the following pair would undergo SN2 faster from the other?

a. CH3CH2CH2I      b. CH3CH2CH2Cl


Complete the following reaction giving major product.

\[\begin{array}{cc}\ce{CH3\phantom{................}}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3\phantom{................}}
\end{array}\]


Complete the following reaction giving major products.


Name the reagent used to bring about the following conversion.

Bromoethane to ethoxyethane


Distinguish between SN1 and SN2 mechanism of substitution reaction.


Convert the following:

Benzyl alcohol to benzyl cyanide


Convert the following:

tert-Butyl bromide to isobutyl bromide


HCl is added to a hydrocarbon ‘A’ \[\ce{(C4H8)}\] to give a compound ‘B’ which on hydrolysis with aqueous alkali forms tertiary alcohol ‘C’ \[\ce{(C4H10O)}\]. Identify ‘A’ ,‘B’ and ‘C’.


Explain the factors affecting SN1 and SN2 mechanism.


In alkaline hydrolysis of tertiary butyl bromide, ____________.


Ethyl bromide undergoes the following reaction:

\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]

Which of the following is a WRONG statement?


The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:

\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]

\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]

The order of the reaction with respect to NO2(g)


How many metameric ethers are represented by the molecular formula C4H10O?


Identify 'B' in the following reaction.

\[\ce{2-Bromobutane ->[KOH alc.][\Delta] A ->[HI] B}\]


What is the major product obtained in the sulphonation of chlorobenzene with concentrated sulphuric acid?


Write the product formed when alkyl halide reacts with silver nitrite.


The order of reactivities of the following alkyl halides for an SN2 reaction is ______.


Which of the following statements is incorrect regarding the dehydrohalogenation of alkenes?


Which among the following statements is not correct about SN2 reaction mechanism?


Observe the following and answer the questions given below:

Name the type of halogen derivative.


Observe the following and answer the question given below:

Comment on the bond length of C-X bond in it.


Define and explain the SN1 mechanism with a suitable example.


Give a reason for the following:

Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/ dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]


Which among the following is NOT benzylic halide?


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