Advertisements
Advertisements
प्रश्न
HCl is added to a hydrocarbon ‘A’ \[\ce{(C4H8)}\] to give a compound ‘B’ which on hydrolysis with aqueous alkali forms tertiary alcohol ‘C’ \[\ce{(C4H10O)}\]. Identify ‘A’ ,‘B’ and ‘C’.
Advertisements
उत्तर
\[\begin{array}{cc}
\phantom{...}\ce{CH3}\phantom{..............................}\ce{CH3}\phantom{..............................}\ce{CH3}\\
|\phantom{..................................}|\phantom{.................................}|\\
\ce{\underset{(A)}{\underset{(C4H8)}{\underset{2-Methylprop-1-ene}{H3C - C = CH2 + HCl}}} ->[Markovnikov][rule] H3C - C - CH3 ->[KOH (aq_.)Hydrolysis][\Delta] H3C - C - CH3}\\
\phantom{...................................}|\phantom{.................................}|\\
\phantom{.....................................}\ce{\underset{(B)}{\underset{2-Chloro-2-methylpropane}{Cl}}\phantom{...............}\ce{\underset{(C)}{\underset{(C4H10O)}{\underset{2-Hydroxy-2-methylpropane}{OH}}}}}
\end{array}\]
APPEARS IN
संबंधित प्रश्न
from the following pair would undergo SN2 faster from the other?
a. CH3CH2CH2I b. CH3CH2CH2Cl
Complete the following reaction giving major products.
\[\ce{CH3 - CH = CH2 ->[HBr][peroxide] A ->[alc. KOH] B}\]
Complete the following reaction giving major products.
\[\begin{array}{cc}\ce{CH3 - CH = CH3 ->[Red P/Br2] A ->[Ag2O/H2O]B}\\|\phantom{.........................}\\
\ce{OH\phantom{.......................}}\end{array}\]
Name the reagent used to bring about the following conversion.
Ethyl bromide to ethyl isocyanide
Convert the following:
Ethanol to propane nitrile
Convert the following:
2-Chloropropane to propan-1-ol
Convert the following:
tert-Butyl bromide to isobutyl bromide
Observe the following and answer the question given below.
Name the type of halogen derivative.
Observe the following and answer the question given below.
Can it react by SN1 mechanism? Justify your answer.
Write the correct order of increasing ease of dehydrohalogenation.
\[\ce{\underset{\text{(I)}}{CH3 - CH2 - CH2 - Cl}}\]
\[\ce{\underset{\text{(II)}}{CH3 - CH(Cl) - CH3}}\]
\[\begin{array}{cc}
\ce{CH3}\\
|\\
\ce{CH3-C-Cl}\phantom{...}\\
|\\
\ce{CH3}\\
\ce{(III)}
\end{array}\]
Explain primary benzylic halide shows higher reactivity by SN1 mechanism than other primary alkyl halide.
In alkaline hydrolysis of tertiary butyl bromide, ____________.
Which of the following is least reactive towards SN1 reactions?
Ethyl bromide undergoes the following reaction:
\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]
Which of the following is a WRONG statement?
Dehydrohalogenation of an alkyl halide is ____________.
What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?
Which of the following is FALSE regarding SN2 reaction mechanism?
Write the product formed when alkyl halide reacts with silver nitrite.
The major product formed when 2-bromobutane is treated with alcoholic KOH is ______.
The order of reactivity of the given haloalkanes towards nucleophiles is:
With which halogen the reactions, of alkanes are explosive?
Explain the dehydrohalogenation reaction of 2-chlorobutane.
Observe the following and answer the questions given below:
Name the type of halogen derivative.
Complete the following reactions giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
What is the action of following on ethyl bromide?
alcoholic sodium hydroxide
Complete the following reaction, giving a major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{...............}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Identify the substrate 'X' in the following reaction.
\[\ce{\underset{}{X + O2} ->[i) Co-naphtenate 423 K][ii) dil HClΔ] \underset{\underset{}{}}{Phenol + Acetone}}\]
