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Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'. -2-Bromobutane→Alc⋅KOHA→BrA2B→NaNHA2C - Chemistry

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प्रश्न

Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.

\[\ce{2-Bromobutane->[Alc.KOH]A->[][Br2]B->[][NaNH2]C}\]

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उत्तर

\[\begin{array}{cc}
\phantom{.}\ce{Br}\phantom{................................................................}\ce{Br}\phantom{.............................................}\\
\phantom{...}|\phantom{..................................................................}|\phantom{................................................}\\
\ce{\underset{\text{2-Bromobutane}}{H3C - CH - CH2CH3}->[Alc.KOH][-KBr]\underset{\underset{(Major) (A)}{But-2-ene}}{H3C - CH = CH - CH3}->[Br2] H3C - CH - CH - CH3 ->[NaNH2][Double dehydrohalogen reaction] \underset{\text{But-2-yne (C)}}{H3C - C ≡ C-CH3}}\\
\phantom{.........}|\\
\phantom{................}\ce{\underset{\text{2,3-Dibromobutane (B)}}{Br}}
\end{array}\]
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अध्याय 10: Halogen Derivatives - Exercises [पृष्ठ २३३]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 10 Halogen Derivatives
Exercises | Q 7. ii. a. | पृष्ठ २३३

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\ce{OH\phantom{.......................}}\end{array}\]


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\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


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\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]


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