Advertisements
Advertisements
प्रश्न
Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.
\[\ce{2-Bromobutane->[Alc.KOH]A->[][Br2]B->[][NaNH2]C}\]
Advertisements
उत्तर
\phantom{.}\ce{Br}\phantom{................................................................}\ce{Br}\phantom{.............................................}\\
\phantom{...}|\phantom{..................................................................}|\phantom{................................................}\\
\ce{\underset{\text{2-Bromobutane}}{H3C - CH - CH2CH3}->[Alc.KOH][-KBr]\underset{\underset{(Major) (A)}{But-2-ene}}{H3C - CH = CH - CH3}->[Br2] H3C - CH - CH - CH3 ->[NaNH2][Double dehydrohalogen reaction] \underset{\text{But-2-yne (C)}}{H3C - C ≡ C-CH3}}\\
\phantom{.........}|\\
\phantom{................}\ce{\underset{\text{2,3-Dibromobutane (B)}}{Br}}
\end{array}\]
संबंधित प्रश्न
Complete the following reaction giving major products.
\[\begin{array}{cc}\ce{CH3 - CH = CH3 ->[Red P/Br2] A ->[Ag2O/H2O]B}\\|\phantom{.........................}\\
\ce{OH\phantom{.......................}}\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}\ce{CH3\phantom{................}}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3\phantom{................}}
\end{array}\]
Complete the following reaction giving major products.

Name the reagent used to bring about the following conversion.
Bromoethane to ethoxyethane
Name the reagent used to bring about the following conversion.
Ethyl bromide to ethyl isocyanide
Convert the following:
Propene to propan-1-ol
HCl is added to a hydrocarbon ‘A’ \[\ce{(C4H8)}\] to give a compound ‘B’ which on hydrolysis with aqueous alkali forms tertiary alcohol ‘C’ \[\ce{(C4H10O)}\]. Identify ‘A’ ,‘B’ and ‘C’.
Observe the following and answer the question given below.

Comment on the bond length of C–X bond in it.
Propane nitrile can be prepared by heating ____________
The following will react faster by SN1 mechanism
Major product of the following reaction is _______________
\[\ce{CH3-CH2-Mg-Br + NH3 ->?}\]
Nucleophilic substitution reaction of 2, 4-dinitrochlorobenzene is faster than p-nitrochlorobenzene. Give reason.
Explain the factors affecting SN1 and SN2 mechanism.
What is dehydrohalogenation? State the rule for the formation of the preferred product of dehydrohalogenation.
The least reactive towards nucleophilic addition reactions is ____________.
Ethyl bromide undergoes the following reaction:
\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]
Which of the following is a WRONG statement?
Which of the following is least reactive towards nucleophilic addition?
How many metameric ethers are represented by the molecular formula C4H10O?
The SN2 reaction of a compound containing an asymmetric carbon atom always gives ____________.
Identify major product 'B' in the following reaction.
\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]
What is the major product obtained in the sulphonation of chlorobenzene with concentrated sulphuric acid?
Write the product formed when alkyl halide reacts with silver nitrite.
Convert the following.
p-Nitrochlorobenzene to p-nitrophenol
The major product formed when 2-bromobutane is treated with alcoholic KOH is ______.
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{...............}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]
