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प्रश्न
What is the action of following on ethyl bromide?
alcoholic sodium hydroxide
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उत्तर
When ethyl bromide is boiled with an alcoholic solution of sodium hydroxide \[\ce{(NaOH)}\], an alkene is formed due to the elimination of hydrogen atoms from carbon and halogen from α-carbon, which is called dehydrohalogenation.
\[\ce{\underset{(Ethyl bromide)}{\overset{\beta\phantom{.............}\alpha\phantom{............}}{CH3 - CH2 - Br}} + \underset{(alc.)}{NaOH} ->[\Delta] \underset{(Ethene)}{CH2 = CH2} + NaBr + H2O}\]
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संबंधित प्रश्न
Complete the following reaction giving major products.
\[\ce{CH3 - CH = CH2 ->[HBr][peroxide] A ->[alc. KOH] B}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}\ce{CH3\phantom{................}}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3\phantom{................}}
\end{array}\]
Name the reagent used to bring about the following conversion.
1-Chloropropane to 1-nitropropane
Name the reagent used to bring about the following conversion.
Ethyl bromide to ethyl isocyanide
Convert the following:
Benzyl alcohol to benzyl cyanide
Convert the following:
Ethanol to propane nitrile
Observe the following and answer the question given below.
Comment on the bond length of C–X bond in it.
Observe the following and answer the question given below.
Can it react by SN1 mechanism? Justify your answer.
Propane nitrile can be prepared by heating ____________
Write the correct order of increasing ease of dehydrohalogenation.
\[\ce{\underset{\text{(I)}}{CH3 - CH2 - CH2 - Cl}}\]
\[\ce{\underset{\text{(II)}}{CH3 - CH(Cl) - CH3}}\]
\[\begin{array}{cc}
\ce{CH3}\\
|\\
\ce{CH3-C-Cl}\phantom{...}\\
|\\
\ce{CH3}\\
\ce{(III)}
\end{array}\]
Explain primary benzylic halide shows higher reactivity by SN1 mechanism than other primary alkyl halide.
Explain aqueous alkaline hydrolysis of tert. butyl bromide.
Which of the following is least reactive towards nucleophilic addition?
What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?
Which of the following carbocation is the most stable?
Which of the following is FALSE regarding SN2 reaction mechanism?
What is the major product obtained in the sulphonation of chlorobenzene with concentrated sulphuric acid?
Convert the following.
p-Nitrochlorobenzene to p-nitrophenol
Which among the following statements is not correct about SN2 reaction mechanism?
With which halogen the reactions, of alkanes are explosive?
Complete the following reaction giving major products.
\[\begin{array}{cc}
\ce{CH3}\phantom{.......}\\
|\phantom{.........}\\
\ce{CH3 - c - CH2 - Cl ->[Na/dry ether]}\\
|\phantom{.........}\\
\ce{CH3}\phantom{.......}
\end{array}\]
Complete the following reactions giving a major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]
Observe the following and answer the questions given below:
Name the type of halogen derivative.
Discuss β - elimination reaction.
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{...............}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{...............}\\
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{...............}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
