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प्रश्न
What is the action of following on ethyl bromide?
alcoholic sodium hydroxide
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उत्तर
When ethyl bromide is boiled with an alcoholic solution of sodium hydroxide \[\ce{(NaOH)}\], an alkene is formed due to the elimination of hydrogen atoms from carbon and halogen from α-carbon, which is called dehydrohalogenation.
\[\ce{\underset{(Ethyl bromide)}{\overset{\beta\phantom{.............}\alpha\phantom{............}}{CH3 - CH2 - Br}} + \underset{(alc.)}{NaOH} ->[\Delta] \underset{(Ethene)}{CH2 = CH2} + NaBr + H2O}\]
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संबंधित प्रश्न
from the following pair would undergo SN2 faster from the other?
a. CH3CH2CH2I b. CH3CH2CH2Cl
Complete the following reaction giving major products.
\[\begin{array}{cc}\ce{CH3 - CH = CH3 ->[Red P/Br2] A ->[Ag2O/H2O]B}\\|\phantom{.........................}\\
\ce{OH\phantom{.......................}}\end{array}\]
Complete the following reaction giving major products.
Give reasons:
Haloarenes are less reactive than haloalkanes.
Convert the following:
Benzyl alcohol to benzyl cyanide
Convert the following:
tert-Butyl bromide to isobutyl bromide
Observe the following and answer the question given below.
Can it react by SN1 mechanism? Justify your answer.
Write the correct order of increasing ease of dehydrohalogenation.
\[\ce{\underset{\text{(I)}}{CH3 - CH2 - CH2 - Cl}}\]
\[\ce{\underset{\text{(II)}}{CH3 - CH(Cl) - CH3}}\]
\[\begin{array}{cc}
\ce{CH3}\\
|\\
\ce{CH3-C-Cl}\phantom{...}\\
|\\
\ce{CH3}\\
\ce{(III)}
\end{array}\]
Explain. Aryl halides are less reactive than alkyl halides towards nucleophilic substitution reactions.
In alkaline hydrolysis of tertiary butyl bromide, ____________.
Ethyl bromide undergoes the following reaction:
\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]
Which of the following is a WRONG statement?
Dehydrohalogenation of an alkyl halide is ____________.
What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?
Write the product formed when alkyl halide reacts with silver nitrite.
Convert the following.
p-Nitrochlorobenzene to p-nitrophenol
The order of reactivities of the following alkyl halides for an SN2 reaction is ______.
The order of reactivity of the given haloalkanes towards nucleophiles is:
With which halogen the reactions, of alkanes are explosive?
Observe the following and answer the question given below:
Can react by SN1 mechanism? Justify your answer.
Complete the following reaction sequences by writing the structural formulae of the organic compounds 'A', 'B' and 'C'.
\[\ce{2-Bromobutan ->[alc. KOH] A ->[][Br2] B ->[][NANH2] C}\]
Define and explain the SN1 mechanism with a suitable example.
Complete the following reaction, giving a major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}
\end{array}\]
Identify the chiral molecule from the following.
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/ dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]
Which of the following pair of compounds on heating gives butanenitrile?
Which among the following is NOT benzylic halide?
