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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

What is the action of following on ethyl bromide? alcoholic sodium hydroxide

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प्रश्न

What is the action of following on ethyl bromide?

alcoholic sodium hydroxide

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लघु उत्तर
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उत्तर

When ethyl bromide is boiled with an alcoholic solution of sodium hydroxide \[\ce{(NaOH)}\], an alkene is formed due to the elimination of hydrogen atoms from carbon and halogen from α-carbon, which is called dehydrohalogenation.

\[\ce{\underset{(Ethyl bromide)}{\overset{\beta\phantom{.............}\alpha\phantom{............}}{CH3 - CH2 - Br}} + \underset{(alc.)}{NaOH} ->[\Delta] \underset{(Ethene)}{CH2 = CH2} + NaBr + H2O}\]

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संबंधित प्रश्‍न

from the following pair would undergo SN2 faster from the other?

a. CH3CH2CH2I      b. CH3CH2CH2Cl


Name the reagent used to bring about the following conversion.

Ethyl bromide to ethyl isocyanide


Arrange the following in the increasing order of boiling points.

  1. 1-Bromopropane
  2. 2- Bromopropane
  3. 1- Bromobutane
  4. 1-Bromo-2-methylpropane

Convert the following:

Ethanol to propane nitrile


Convert the following:

2-Chloropropane to propan-1-ol


Observe the following and answer the question given below.

Comment on the bond length of C–X bond in it.


Write the correct order of increasing ease of dehydrohalogenation.

\[\ce{\underset{\text{(I)}}{CH3 - CH2 - CH2 - Cl}}\]

\[\ce{\underset{\text{(II)}}{CH3 - CH(Cl) - CH3}}\]

\[\begin{array}{cc}
\ce{CH3}\\
|\\
\ce{CH3-C-Cl}\phantom{...}\\
|\\
\ce{CH3}\\
\ce{(III)}
\end{array}\]


Which of the following is least reactive towards SN1 reactions?


Ethyl bromide undergoes the following reaction:

\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]

Which of the following is a WRONG statement?


Which of the following is least reactive towards nucleophilic addition?


The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:

\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]

\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]

The order of the reaction with respect to NO2(g)


What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?


\[\ce{C6H5CH2Cl + KCN(alc) -> X + Y}\]

Compounds X and Y are ____________.


Identify 'B' in the following reaction.

\[\ce{2-Bromobutane ->[KOH alc.][\Delta] A ->[HI] B}\]


Convert the following.

p-Nitrochlorobenzene to p-nitrophenol


The order of reactivities of the following alkyl halides for an SN2 reaction is ______.


Which among the following statements is not correct about SN2 reaction mechanism?


With which halogen the reactions, of alkanes are explosive?


Observe the following and answer the question given below:

Comment on the bond length of C-X bond in it.


Define and explain the SN1 mechanism with a suitable example.


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]


Give a reason for the following:

Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]


Identify the substrate 'X' in the following reaction.

\[\ce{\underset{}{X + O2} ->[i) Co-naphtenate 423 K][ii) dil HClΔ] \underset{\underset{}{}}{Phenol + Acetone}}\]


Which among the following is NOT benzylic halide?


Which of the following reagent is used for conversion of alkyl halide into nitrile?


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