Advertisements
Advertisements
प्रश्न
For the reaction A + B → P.
If [B] is doubled at constant [A], the rate of reaction doubled. If [A] is triple and [B] is doubled, the rate of reaction increases by a factor of 6. Calculate the rate law equation.
Advertisements
उत्तर
Given: A + B → P
∴ Rate of reaction,
rate = k[A]x [B]y ...(i)
If [B] is doubled at constant [A], the rate of reaction doubled.
∴ 2 × rate = k[A]x [2B]y
∴ 2 × rate = k[A]x 2y [2B]y ...(ii)
If [A] is tripled and [B] is doubled, the rate of reaction increases by a factor of 6.
∴ 6 × rate = k[3A]x [2B]y
6 × rate = 3x k[3A]x 2y [B]y ...(iii)
Divide equation (ii) by (i), we get
`(2 xx "rate")/"rate" = (k[A]^x 2^y[B]^y)/(k[A]^x [B]^y)`
21 = 2y
∴ y = 1
Now divide equation (iii) by (i), we get
`(6 xx "rate")/"rate" = (3^x k[A]^x 2^y [B]^y)/(k[A]^x [B]^y)`
6 = 3x2y
= 3x × 2 ...(∵ y = 1)
∴ x = 1
Now, x = 1 and y = 1 values should be written in the equation (i)
∴ The rate law can be written as
rate = k[A]1 [B]1
rate = k[A][B]
APPEARS IN
संबंधित प्रश्न
Choose the most correct option.
The order of the reaction for which the units of the rate constant are mol dm-3 s-1 is _______.
Choose the most correct option.
The rate constant for the reaction \[\ce{2N2O5_{(g)} -> 2N2O4_{(g)} + O2_{(g)}}\] is `4.98 xx 10^-4 "s"^-1`. The order of reaction is _____________.
Choose the most correct option.
Slope of the graph ln[A]t versus t for first-order reaction is _________.
Choose the most correct option.
The reaction, \[\ce{3ClO- -> ClO^-3 + 2Cl-}\] occurs in two steps,
(i) \[\ce{2ClO- -> ClO^-2}\]
(ii) \[\ce{ClO^-2 + ClO- -> ClO^-_3 + Cl-}\]
The reaction intermediate is _______.
The elementary reaction \[\ce{O3_{(g)} + O_{(g)} -> 2O2_{(g)}}\] is ______.
Choose the most correct option.
Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.
Answer the following in one or two sentences.
For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\], rate law is rate = \[\ce{k[CH3Br][OH^\ominus]}\]
How does reaction rate changes if \[\ce{[OH^\ominus]}\] is decreased by a factor of 5?
Answer the following in brief.
For the reaction 2A + B → products, find the rate law from the following data.
| [A]/M | [B]/M | rate/M s-1 |
| 0.3 | 0.05 | 0.15 |
| 0.6 | 0.05 | 0.30 |
| 0.6 | 0.2 | 1.20 |
A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is _______.
The rate law relates to the rate of a chemical reaction in terms of _______.
In a first-order reaction A → B, 60% of a given sample of a compound decomposes in 45 mins. What is the half-life of reaction? Also, write the rate law equation for the above first-order reaction.
For the reaction, \[\ce{N2(g) + 3H2(g) -> 2NH3(g); \Delta H}\] is equal to ______.
Select the rate law that corresponds to the data shown for the following reaction:
\[\ce{A + B -> C}\]
| Exp. | [A] mol dm−3 |
[B] mol dm−3 |
Initial Rate mol dm−3 |
| 1. | 0.012 | 0.035 | 0.10 |
| 2. | 0.024 | 0.070 | 0.80 |
| 3. | 0.024 | 0.035 | 0.10 |
| 4. | 0.012 | 0.070 | 0.80 |
The rate law for the reaction \[\ce{A + B + C -> Product}\] is expressed as Rate = k[A]2 [B]1 [C]0. What is the overall order of the reaction?
The rate law for the reaction \[\ce{2NO_{(g)} + O2_{(g)} -> 2NO2_{(g)}}\] is rate = k[NO]2 [O2] , then which among the following statement is correct?
In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.
What is the order of reaction for decomposition of gaseous acetaldehyde?
For the reaction \[\ce{2A + B -> 3C + D}\], which among the following is NOT the correct rate law expression?
For the reaction \[\ce{4NH3 + 5O2 -> 4NO + 6H2O}\], the rate of disappearance of NH3 is 3.6 × 10-3 M/s. What is the rate of formation of water?
The correct order of raaii of F, F-, O and O2- is ______.
Write the rate law for the following reaction:
A reaction that is zero order in A and second order in B.
Write the rate law for the following reaction:
A reaction that is second order in NO and first order in Br2.
The rate constant of a reaction ______.
For the reaction 2A + B → A2B find the rate of decrease of [B].
