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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

For the reaction 2NOX(g)+2HX2(g)⟶NX2(g)+2HX2OX(g), The rate law is, rate = k[NO]2 [H2]. What is the overall order of reaction?

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प्रश्न

For the reaction \[\ce{2NO_{(g)} + 2H_{2(g)} -> N_{2(g)} + 2H2O_{(g)}}\],

The rate law is, rate = k[NO]2 [H2].

What is the overall order of reaction?

एका वाक्यात उत्तर
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उत्तर

The reaction is of second order in NO and first order in H2 and hence, the reaction is third order overall.

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पाठ 6: Chemical Kinetics - Very short answer questions

संबंधित प्रश्‍न

Choose the most correct option.

The order of the reaction for which the units of the rate constant are mol dm-3 s-1 is _______.


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The rate constant for the reaction \[\ce{2N2O5_{(g)} -> 2N2O4_{(g)} + O2_{(g)}}\] is `4.98 xx 10^-4 "s"^-1`. The order of reaction is _____________.


The time required for 90% completion of a certain first-order reaction is t. The time required for 99.9% completion will be _________.


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Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.


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For an endothermic reaction, X ⇌ Y. If Ef is the activation energy of the forward reaction and Er that for the reverse reaction, which of the following is correct?


Answer the following in one or two sentences.

For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\], rate law is rate = \[\ce{k[CH3Br][OH^\ominus]}\]

How does reaction rate changes if \[\ce{[OH^\ominus]}\] is decreased by a factor of 5?


Answer the following in brief.

For the reaction 2A + B → products, find the rate law from the following data.

[A]/M [B]/M rate/M s-1
0.3 0.05 0.15
0.6 0.05 0.30
0.6 0.2 1.20

The rate law relates to the rate of a chemical reaction in terms of _______.


For the reaction 2A + B → C, rate of disappearance of A 0.076 mol s –1.

  1. What is the rate of formation of C?
  2. What is the rate of consumption of B?
  3. What is the rate of the overall reaction?

In a hypothetical reaction,

\[\ce{2A + B -> Products}\]. Rate = k [A]2 [B]

Molar concentration of 'B' is kept constant and molar concentration of 'A' is tripled, then the rate of reaction will ____________.


The rate constant of a first order reaction whose half-life is 480 seconds, is ____________.


For the non-stoichiometric reaction

\[\ce{2A + B -> C + D}\], the following kinetic data were obtained in three separate experiments, all at 298 K.

Initial concentration
(A)
Initial concentration
(B)
Initial rate of formation of C
(mol dm−3 s−1)
0.1 M 0.1 M 1.2 × 10−3
0.1 M 0.2 M 1.2 × 10−3
0.2 M 0.1 M 2.4 × 10−3

The rate law for the formation of C is:


For a hypothetical reaction \[\ce{A + B -> C}\], it is found that doubling the concentration of A increases the rate by 8 times and doubling the concentration of B increases the rate by 4 times. The overall order of the reaction is ____________.


Select the rate law that corresponds to the data shown for the following reaction:

\[\ce{A + B -> C}\]

Exp. [A]
mol dm−3
[B]
mol dm−3
Initial Rate
mol dm−3
1. 0.012 0.035 0.10
2. 0.024 0.070 0.80
3. 0.024 0.035 0.10
4. 0.012 0.070 0.80

The rate law for the reaction \[\ce{A + B + C -> Product}\] is expressed as Rate = k[A]2 [B]1 [C]0. What is the overall order of the reaction?


Consider the reaction \[\ce{2A + 2B -> C + 2D}\], if concentration of A is doubled at constant [B], rate increases by a factor 4. If concentration B is doubled at constant [A] the rate is doubled. Rate law of the reaction is ____________.


What is the order of reaction for decomposition of gaseous acetaldehyde?


In the reaction \[\ce{2SO_{2_{(g)}} O_{2_{(g)}} -> 2SO_{3_{(g)}}}\], the rate of disappearance of SO2 is 1.28 × 10-5 M/s. What is the rate of appearance of SO3?


For the reaction \[\ce{2A + B -> 3C + D}\], which among the following is NOT the correct rate law expression?


Molarity of H2SO4 is 18 M. Its density is 1.8 g/ml. Hence molality is ______.


Which of the following statement is not true for a reaction having rate law r = k[H2][I2]?


Write the rate law for the following reaction:

A reaction that is zero order in A and second order in B.


For a chemical reaction A → 7 products, the rate of reaction doubles when the concentration of A is increased by a factor 4. The order of the reaction is ______.


The rate constant for a first-order reaction whose half-life is 480 seconds is ______.


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