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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Choose the most correct option. Rate law for the reaction, 2NO+ClX2⟶2NOCl is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.

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प्रश्न

Choose the most correct option.

Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.

पर्याय

  • increase in temperature

  • increase of concentration of NO

  • increase of concentration of Cl2

  • increase of concentrations of both Cl2 and NO

MCQ
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उत्तर

Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with increase in temperature.

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पाठ 6: Chemical Kinetics - Exercises [पृष्ठ १३५]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 6 Chemical Kinetics
Exercises | Q 1. ix. | पृष्ठ १३५

संबंधित प्रश्‍न

Choose the most correct option.

The order of the reaction for which the units of the rate constant are mol dm-3 s-1 is _______.


The time required for 90% completion of a certain first-order reaction is t. The time required for 99.9% completion will be _________.


Choose the most correct option.

Slope of the graph ln[A]t versus t for first-order reaction is _________.


Choose the most correct option.

The reaction, \[\ce{3ClO- -> ClO^-3 + 2Cl-}\] occurs in two steps, 

(i) \[\ce{2ClO- -> ClO^-2}\]

(ii) \[\ce{ClO^-2 + ClO- -> ClO^-_3 + Cl-}\] 

The reaction intermediate is _______.


Answer the following in one or two sentences.

For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\], rate law is rate = \[\ce{k[CH3Br][OH^\ominus]}\]

How does reaction rate changes if \[\ce{[OH^\ominus]}\] is decreased by a factor of 5?


Answer the following in one or two sentences.

For the reaction,

\[\ce{CH3Br_{(aq)} + OH^-_{ (aq)} -> CH3OH^-_{ (aq)} + Br^-_{ (aq)}}\], rate law is rate = k`["CH"_3"Br"]["OH"^-]`

What is the change in rate if concentrations of both reactants are doubled?


The rate law relates to the rate of a chemical reaction in terms of _______.


Order of reaction for which unit of rate constant is mol dm–3 s–1 is _______.


A reaction occurs in the following steps:

Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)

Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)

  1. Write the equation of overall reaction.
  2. Write the rate law.
  3. Identify reaction intermediate.

For the reaction 2A + B → C, rate of disappearance of A 0.076 mol s –1.

  1. What is the rate of formation of C?
  2. What is the rate of consumption of B?
  3. What is the rate of the overall reaction?

In a first-order reaction A → B, 60% of a given sample of a compound decomposes in 45 mins. What is the half-life of reaction? Also, write the rate law equation for the above first-order reaction.


The rate constant of a first order reaction whose half-life is 480 seconds, is ____________.


For the reaction, \[\ce{N2(g) + 3H2(g) -> 2NH3(g); \Delta H}\] is equal to ______.


For a chemical reaction rate law is, rate = k[A]2[B]. If [A] is doubled at constant [B], the rate of reaction ______.


For a hypothetical reaction \[\ce{A + B -> C}\], it is found that doubling the concentration of A increases the rate by 8 times and doubling the concentration of B increases the rate by 4 times. The overall order of the reaction is ____________.


Consider the reaction \[\ce{2A + 2B -> C + 2D}\], if concentration of A is doubled at constant [B], rate increases by a factor 4. If concentration B is doubled at constant [A] the rate is doubled. Rate law of the reaction is ____________.


In the reaction \[\ce{A + B2 -> AB + B}\], the rate of reaction is directly proportional to the concentration of A and independent on the concentration of B2. What is the rate law expression?


The reaction \[\ce{A + B -> P}\], is second order in A and first order in B. What is the rate law for the reaction?


What is the order of reaction for decomposition of gaseous acetaldehyde?


For the reaction \[\ce{4NH3 + 5O2 -> 4NO + 6H2O}\], the rate of disappearance of NH3 is 3.6 × 10-3 M/s. What is the rate of formation of water?


Which of the following statement is not true for a reaction having rate law r = k[H2][I2]?


Write the rate law for the following reaction:

A reaction that is zero order in A and second order in B.


The rate constant of a reaction ______.


For the reaction A + B → P.

If [B] is doubled at constant [A], the rate of reaction doubled. If [A] is triple and [B] is doubled, the rate of reaction increases by a factor of 6. Calculate the rate law equation.


For the reaction 2A + B → A2B find the rate of decrease of [B].


`t_(1/4)` can be taken as the time taken for the concentration of a reactant to drop to `3/4` of its initial value. If the rate constant for a first order reaction is k, the `t_(1/4)` can be written as ______.


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