मराठी
महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Answer the following in one or two sentences. For the reaction,What is the change in rate if concentrations of both reactants are doubled?

Advertisements
Advertisements

प्रश्न

Answer the following in one or two sentences.

For the reaction,

\[\ce{CH3Br_{(aq)} + OH^-_{ (aq)} -> CH3OH^-_{ (aq)} + Br^-_{ (aq)}}\], rate law is rate = k`["CH"_3"Br"]["OH"^-]`

What is the change in rate if concentrations of both reactants are doubled?

टीपा लिहा
Advertisements

उत्तर

For the reaction

\[\ce{CH3Br_{(aq)} + Br^-_{ (aq)} -> CH3OH_{ (aq)} + Br^-_{ (aq)}}\]

Rate = k`["CH"_3"Br"]["OH"^-]`

If concentrations of `"CH"_3"Br"` and `"OH"^-` are doubled, rate will increase by a factor of 4.

shaalaa.com
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 6: Chemical Kinetics - Exercises [पृष्ठ १३६]

APPEARS IN

बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 6 Chemical Kinetics
Exercises | Q 2. ii. b. | पृष्ठ १३६

संबंधित प्रश्‍न

What is the half life of a first order reaction if time required to decrease concentration of reactant from 0.8 M to 0.2 M is 12 h?


Choose the most correct option.

The reaction, \[\ce{3ClO- -> ClO^-3 + 2Cl-}\] occurs in two steps, 

(i) \[\ce{2ClO- -> ClO^-2}\]

(ii) \[\ce{ClO^-2 + ClO- -> ClO^-_3 + Cl-}\] 

The reaction intermediate is _______.


Choose the most correct option.

For an endothermic reaction, X ⇌ Y. If Ef is the activation energy of the forward reaction and Er that for the reverse reaction, which of the following is correct?


Answer the following in brief.

For the reaction 2A + B → products, find the rate law from the following data.

[A]/M [B]/M rate/M s-1
0.3 0.05 0.15
0.6 0.05 0.30
0.6 0.2 1.20

A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is _______.


The rate law relates to the rate of a chemical reaction in terms of _______.


Define order of reaction with suitable examples.


For the reaction 2A + B → C, rate of disappearance of A 0.076 mol s –1.

  1. What is the rate of formation of C?
  2. What is the rate of consumption of B?
  3. What is the rate of the overall reaction?

In a first-order reaction A → B, 60% of a given sample of a compound decomposes in 45 mins. What is the half-life of reaction? Also, write the rate law equation for the above first-order reaction.


In a hypothetical reaction,

\[\ce{2A + B -> Products}\]. Rate = k [A]2 [B]

Molar concentration of 'B' is kept constant and molar concentration of 'A' is tripled, then the rate of reaction will ____________.


The rate constant of a first order reaction whose half-life is 480 seconds, is ____________.


For the non-stoichiometric reaction

\[\ce{2A + B -> C + D}\], the following kinetic data were obtained in three separate experiments, all at 298 K.

Initial concentration
(A)
Initial concentration
(B)
Initial rate of formation of C
(mol dm−3 s−1)
0.1 M 0.1 M 1.2 × 10−3
0.1 M 0.2 M 1.2 × 10−3
0.2 M 0.1 M 2.4 × 10−3

The rate law for the formation of C is:


The rate law for a reaction between the substances A and B is given by, rate = k[A]n [B]m. On halving the concentration of A and doubling the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as ____________.


For a chemical reaction rate law is, rate = k[A]2[B]. If [A] is doubled at constant [B], the rate of reaction ______.


In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.


What is the order of reaction for decomposition of gaseous acetaldehyde?


What is the molecularity and order of the following reaction if rate law is, rate = k[O3][O] respectively.

\[\ce{O_{3(g)} + O_{(g)} -> 2O_{2(g)}}\]


For the reaction \[\ce{4NH3 + 5O2 -> 4NO + 6H2O}\], the rate of disappearance of NH3 is 3.6 × 10-3 M/s. What is the rate of formation of water?


Molarity of H2SO4 is 18 M. Its density is 1.8 g/ml. Hence molality is ______.


Write the rate law for the following reaction:

A reaction that is zero order in A and second order in B.


Write the rate law for the following reaction:

A reaction that is second order in NO and first order in Br2.


For the reaction 2A + B → A2B find the rate of decrease of [B].


The rate constant for a first-order reaction whose half-life is 480 seconds is ______.


`t_(1/4)` can be taken as the time taken for the concentration of a reactant to drop to `3/4` of its initial value. If the rate constant for a first order reaction is k, the `t_(1/4)` can be written as ______.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×