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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is _______.

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प्रश्न

A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is _______.

पर्याय

  • 230.3 min

  • 100 min

  • 230 min

  • 125 min

MCQ
रिकाम्या जागा भरा
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उत्तर

A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is 230.3 min.

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पाठ 6: Chemical Kinetics - Multiple choice questions

संबंधित प्रश्‍न

The elementary reaction \[\ce{O3_{(g)} + O_{(g)} -> 2O2_{(g)}}\] is ______.


Choose the most correct option.

For an endothermic reaction, X ⇌ Y. If Ef is the activation energy of the forward reaction and Er that for the reverse reaction, which of the following is correct?


Answer the following in one or two sentences.

For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\], rate law is rate = \[\ce{k[CH3Br][OH^\ominus]}\]

How does reaction rate changes if \[\ce{[OH^\ominus]}\] is decreased by a factor of 5?


Answer the following in brief.

For the reaction 2A + B → products, find the rate law from the following data.

[A]/M [B]/M rate/M s-1
0.3 0.05 0.15
0.6 0.05 0.30
0.6 0.2 1.20

Answer the following in one or two sentences.

For the reaction,

\[\ce{CH3Br_{(aq)} + OH^-_{ (aq)} -> CH3OH^-_{ (aq)} + Br^-_{ (aq)}}\], rate law is rate = k`["CH"_3"Br"]["OH"^-]`

What is the change in rate if concentrations of both reactants are doubled?


The rate law relates to the rate of a chemical reaction in terms of _______.


Define order of reaction with suitable examples.


A reaction occurs in the following steps:

Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)

Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)

  1. Write the equation of overall reaction.
  2. Write the rate law.
  3. Identify reaction intermediate.

In a first-order reaction A → B, 60% of a given sample of a compound decomposes in 45 mins. What is the half-life of reaction? Also, write the rate law equation for the above first-order reaction.


In a hypothetical reaction,

\[\ce{2A + B -> Products}\]. Rate = k [A]2 [B]

Molar concentration of 'B' is kept constant and molar concentration of 'A' is tripled, then the rate of reaction will ____________.


For the reaction, \[\ce{N2(g) + 3H2(g) -> 2NH3(g); \Delta H}\] is equal to ______.


A gaseous hypothetical chemical equation \[\ce{2A ⇌ 4B + C}\] is carried out in a closed vessel. The concentration of B is found to increase by 5 × 10−3 mol dm−3 in 10 second. The rate of ____________.


The rate law for a reaction between the substances A and B is given by, rate = k[A]n [B]m. On halving the concentration of A and doubling the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as ____________.


For a chemical reaction rate law is, rate = k[A]2[B]. If [A] is doubled at constant [B], the rate of reaction ______.


Select the rate law that corresponds to the data shown for the following reaction:

\[\ce{A + B -> C}\]

Exp. [A]
mol dm−3
[B]
mol dm−3
Initial Rate
mol dm−3
1. 0.012 0.035 0.10
2. 0.024 0.070 0.80
3. 0.024 0.035 0.10
4. 0.012 0.070 0.80

The order of the reaction occurring by following mechanism should be:

(i) \[\ce{A2 + B2 -> AB2 + A (slow)}\]

(ii) \[\ce{A + B2 -> AB2 (fast)}\]


The rate law for the reaction \[\ce{2NO_{(g)} + O2_{(g)} -> 2NO2_{(g)}}\] is rate = k[NO]2 [O2] , then which among the following statement is correct?


In the reaction \[\ce{A + B2 -> AB + B}\], the rate of reaction is directly proportional to the concentration of A and independent on the concentration of B2. What is the rate law expression?


For the reaction \[\ce{2A + B -> 3C + D}\], which among the following is NOT the correct rate law expression?


For the reaction \[\ce{4NH3 + 5O2 -> 4NO + 6H2O}\], the rate of disappearance of NH3 is 3.6 × 10-3 M/s. What is the rate of formation of water?


Molarity of H2SO4 is 18 M. Its density is 1.8 g/ml. Hence molality is ______.


Which of the following unit is used to express the rate of a reaction?


Write the rate law for the following reaction:

A reaction that is second order in NO and first order in Br2.


The rate constant of a reaction ______.


For the reaction A + B → P.

If [B] is doubled at constant [A], the rate of reaction doubled. If [A] is triple and [B] is doubled, the rate of reaction increases by a factor of 6. Calculate the rate law equation.


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