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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is _______. - Chemistry

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प्रश्न

A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is _______.

पर्याय

  • 230.3 min

  • 100 min

  • 230 min

  • 125 min

MCQ
रिकाम्या जागा भरा
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उत्तर

A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is 230.3 min.

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Rate of Reaction and Reactant Concentration
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पाठ 6: Chemical Kinetics - Multiple choice questions

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संबंधित प्रश्‍न

The time required for 90% completion of a certain first-order reaction is t. The time required for 99.9% completion will be _________.


Choose the most correct option.

Slope of the graph ln[A]t versus t for first-order reaction is _________.


What is the half life of a first order reaction if time required to decrease concentration of reactant from 0.8 M to 0.2 M is 12 h?


Choose the most correct option.

For an endothermic reaction, X ⇌ Y. If Ef is the activation energy of the forward reaction and Er that for the reverse reaction, which of the following is correct?


The rate law relates to the rate of a chemical reaction in terms of _______.


Order of reaction for which unit of rate constant is mol dm–3 s–1 is _______.


Define order of reaction with suitable examples.


A reaction occurs in the following steps:

Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)

Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)

  1. Write the equation of overall reaction.
  2. Write the rate law.
  3. Identify reaction intermediate.

For the reaction 2A + B → C, rate of disappearance of A 0.076 mol s –1.

  1. What is the rate of formation of C?
  2. What is the rate of consumption of B?
  3. What is the rate of the overall reaction?

In a hypothetical reaction,

\[\ce{2A + B -> Products}\]. Rate = k [A]2 [B]

Molar concentration of 'B' is kept constant and molar concentration of 'A' is tripled, then the rate of reaction will ____________.


For the non-stoichiometric reaction

\[\ce{2A + B -> C + D}\], the following kinetic data were obtained in three separate experiments, all at 298 K.

Initial concentration
(A)
Initial concentration
(B)
Initial rate of formation of C
(mol dm−3 s−1)
0.1 M 0.1 M 1.2 × 10−3
0.1 M 0.2 M 1.2 × 10−3
0.2 M 0.1 M 2.4 × 10−3

The rate law for the formation of C is:


Select the rate law that corresponds to the data shown for the following reaction:

\[\ce{A + B -> C}\]

Exp. [A]
mol dm−3
[B]
mol dm−3
Initial Rate
mol dm−3
1. 0.012 0.035 0.10
2. 0.024 0.070 0.80
3. 0.024 0.035 0.10
4. 0.012 0.070 0.80

The order of the reaction occurring by following mechanism should be:

(i) \[\ce{A2 + B2 -> AB2 + A (slow)}\]

(ii) \[\ce{A + B2 -> AB2 (fast)}\]


Consider the reaction \[\ce{2A + 2B -> C + 2D}\], if concentration of A is doubled at constant [B], rate increases by a factor 4. If concentration B is doubled at constant [A] the rate is doubled. Rate law of the reaction is ____________.


In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.


What is the order of reaction for decomposition of gaseous acetaldehyde?


What is the molecularity and order of the following reaction if rate law is, rate = k[O3][O] respectively.

\[\ce{O_{3(g)} + O_{(g)} -> 2O_{2(g)}}\]


For the reaction \[\ce{4NH3 + 5O2 -> 4NO + 6H2O}\], the rate of disappearance of NH3 is 3.6 × 10-3 M/s. What is the rate of formation of water?


Which of the following unit is used to express the rate of a reaction?


Which of the following statement is not true for a reaction having rate law r = k[H2][I2]?


The correct order of raaii of F, F-, O and O2- is ______.


Write the rate law for the following reaction:

A reaction that is zero order in A and second order in B.


The rate constant of a reaction ______.


For the reaction A + B → P.

If [B] is doubled at constant [A], the rate of reaction doubled. If [A] is triple and [B] is doubled, the rate of reaction increases by a factor of 6. Calculate the rate law equation.


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