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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Answer the following in one or two sentences. For the reaction, CHA3BrA(aq)+OHA−A(aq)⟶CHA3OHA⊖A(aq)+BrA⊖A(aq), rate law is rate = k[CHA3Br][OHA⊖] How does reaction rate changes if [OHA⊖] is decreased

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प्रश्न

Answer the following in one or two sentences.

For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\], rate law is rate = \[\ce{k[CH3Br][OH^\ominus]}\]

How does reaction rate changes if \[\ce{[OH^\ominus]}\] is decreased by a factor of 5?

लघु उत्तर
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उत्तर

For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\]

Rate = \[\ce{k[CH3Br][OH^\ominus]}\]

If \[\ce{OH^\ominus}\] is decreased by a factor of 5, keeping \[\ce{CH3Br}\] constant rate will decrease by a factor of 5.

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पाठ 6: Chemical Kinetics - Exercises [पृष्ठ १३६]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 6 Chemical Kinetics
Exercises | Q 2. ii. a. | पृष्ठ १३६

संबंधित प्रश्‍न

Choose the most correct option.

The order of the reaction for which the units of the rate constant are mol dm-3 s-1 is _______.


Choose the most correct option.

Slope of the graph ln[A]t versus t for first-order reaction is _________.


Choose the most correct option.

Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.


Answer the following in one or two sentences.

For the reaction,

\[\ce{CH3Br_{(aq)} + OH^-_{ (aq)} -> CH3OH^-_{ (aq)} + Br^-_{ (aq)}}\], rate law is rate = k`["CH"_3"Br"]["OH"^-]`

What is the change in rate if concentrations of both reactants are doubled?


The rate law relates to the rate of a chemical reaction in terms of _______.


Order of reaction for which unit of rate constant is mol dm–3 s–1 is _______.


Define order of reaction with suitable examples.


For the reaction 2A + B → C, rate of disappearance of A 0.076 mol s –1.

  1. What is the rate of formation of C?
  2. What is the rate of consumption of B?
  3. What is the rate of the overall reaction?

In a first-order reaction A → B, 60% of a given sample of a compound decomposes in 45 mins. What is the half-life of reaction? Also, write the rate law equation for the above first-order reaction.


A gaseous hypothetical chemical equation \[\ce{2A ⇌ 4B + C}\] is carried out in a closed vessel. The concentration of B is found to increase by 5 × 10−3 mol dm−3 in 10 second. The rate of ____________.


The rate law for a reaction between the substances A and B is given by, rate = k[A]n [B]m. On halving the concentration of A and doubling the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as ____________.


Select the rate law that corresponds to the data shown for the following reaction:

\[\ce{A + B -> C}\]

Exp. [A]
mol dm−3
[B]
mol dm−3
Initial Rate
mol dm−3
1. 0.012 0.035 0.10
2. 0.024 0.070 0.80
3. 0.024 0.035 0.10
4. 0.012 0.070 0.80

The order of the reaction occurring by following mechanism should be:

(i) \[\ce{A2 + B2 -> AB2 + A (slow)}\]

(ii) \[\ce{A + B2 -> AB2 (fast)}\]


In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.


Which of the following unit is used to express the rate of a reaction?


Which of the following statement is not true for a reaction having rate law r = k[H2][I2]?


The correct order of raaii of F, F-, O and O2- is ______.


Write the rate law for the following reaction:

A reaction that is zero order in A and second order in B.


Write the rate law for the following reaction:

A reaction that is second order in NO and first order in Br2.


For a chemical reaction A → 7 products, the rate of reaction doubles when the concentration of A is increased by a factor 4. The order of the reaction is ______.


The rate constant of a reaction ______.


For the reaction A + B → P.

If [B] is doubled at constant [A], the rate of reaction doubled. If [A] is triple and [B] is doubled, the rate of reaction increases by a factor of 6. Calculate the rate law equation.


For the reaction 2A + B → A2B find the rate of decrease of [B].


The rate constant for the reaction,

2N2O5(g) → 2N2O4(g) + O2(g) is 4.98 × 10-4 s-1.

What is the order of reaction?


The rate constant for a first-order reaction whose half-life is 480 seconds is ______.


`t_(1/4)` can be taken as the time taken for the concentration of a reactant to drop to `3/4` of its initial value. If the rate constant for a first order reaction is k, the `t_(1/4)` can be written as ______.


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