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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Answer the following in one or two sentences. For the reaction, CHA3BrA(aq)+OHA−A(aq)⟶CHA3OHA⊖A(aq)+BrA⊖A(aq), rate law is rate = k[CHA3Br][OHA⊖] How does reaction rate changes if [OHA⊖] is decreased

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प्रश्न

Answer the following in one or two sentences.

For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\], rate law is rate = \[\ce{k[CH3Br][OH^\ominus]}\]

How does reaction rate changes if \[\ce{[OH^\ominus]}\] is decreased by a factor of 5?

लघु उत्तर
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उत्तर

For the reaction, \[\ce{CH3Br_{(aq)} + OH^{-}_{(aq)} -> CH3OH^{\ominus}_{(aq)} + Br^{\ominus}_{(aq)}}\]

Rate = \[\ce{k[CH3Br][OH^\ominus]}\]

If \[\ce{OH^\ominus}\] is decreased by a factor of 5, keeping \[\ce{CH3Br}\] constant rate will decrease by a factor of 5.

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पाठ 6: Chemical Kinetics - Exercises [पृष्ठ १३६]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 6 Chemical Kinetics
Exercises | Q 2. ii. a. | पृष्ठ १३६

संबंधित प्रश्‍न

Choose the most correct option.

The order of the reaction for which the units of the rate constant are mol dm-3 s-1 is _______.


Choose the most correct option.

The rate constant for the reaction \[\ce{2N2O5_{(g)} -> 2N2O4_{(g)} + O2_{(g)}}\] is `4.98 xx 10^-4 "s"^-1`. The order of reaction is _____________.


The time required for 90% completion of a certain first-order reaction is t. The time required for 99.9% completion will be _________.


Choose the most correct option.

Slope of the graph ln[A]t versus t for first-order reaction is _________.


What is the half life of a first order reaction if time required to decrease concentration of reactant from 0.8 M to 0.2 M is 12 h?


Answer the following in one or two sentences.

For the reaction,

\[\ce{CH3Br_{(aq)} + OH^-_{ (aq)} -> CH3OH^-_{ (aq)} + Br^-_{ (aq)}}\], rate law is rate = k`["CH"_3"Br"]["OH"^-]`

What is the change in rate if concentrations of both reactants are doubled?


Write four key points about order of reaction.


Define order of reaction with suitable examples.


A reaction occurs in the following steps:

Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)

Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)

  1. Write the equation of overall reaction.
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For the reaction 2A + B → C, rate of disappearance of A 0.076 mol s –1.

  1. What is the rate of formation of C?
  2. What is the rate of consumption of B?
  3. What is the rate of the overall reaction?

In a hypothetical reaction,

\[\ce{2A + B -> Products}\]. Rate = k [A]2 [B]

Molar concentration of 'B' is kept constant and molar concentration of 'A' is tripled, then the rate of reaction will ____________.


The rate constant of a first order reaction whose half-life is 480 seconds, is ____________.


A gaseous hypothetical chemical equation \[\ce{2A ⇌ 4B + C}\] is carried out in a closed vessel. The concentration of B is found to increase by 5 × 10−3 mol dm−3 in 10 second. The rate of ____________.


For a hypothetical reaction \[\ce{A + B -> C}\], it is found that doubling the concentration of A increases the rate by 8 times and doubling the concentration of B increases the rate by 4 times. The overall order of the reaction is ____________.


The order of the reaction occurring by following mechanism should be:

(i) \[\ce{A2 + B2 -> AB2 + A (slow)}\]

(ii) \[\ce{A + B2 -> AB2 (fast)}\]


In the reaction \[\ce{A + B2 -> AB + B}\], the rate of reaction is directly proportional to the concentration of A and independent on the concentration of B2. What is the rate law expression?


In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.


In the reaction \[\ce{2SO_{2_{(g)}} O_{2_{(g)}} -> 2SO_{3_{(g)}}}\], the rate of disappearance of SO2 is 1.28 × 10-5 M/s. What is the rate of appearance of SO3?


For the reaction \[\ce{4NH3 + 5O2 -> 4NO + 6H2O}\], the rate of disappearance of NH3 is 3.6 × 10-3 M/s. What is the rate of formation of water?


Which of the following unit is used to express the rate of a reaction?


The correct order of raaii of F, F-, O and O2- is ______.


Write the rate law for the following reaction:

A reaction that is zero order in A and second order in B.


The rate constant of a reaction ______.


For the reaction 2A + B → A2B find the rate of decrease of [B].


The rate constant for the reaction,

2N2O5(g) → 2N2O4(g) + O2(g) is 4.98 × 10-4 s-1.

What is the order of reaction?


The rate constant for a first-order reaction whose half-life is 480 seconds is ______.


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