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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Choose the most correct option. Slope of the graph ln[A]t versus t for first-order reaction is _________. - Chemistry

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प्रश्न

Choose the most correct option.

Slope of the graph ln[A]t versus t for first-order reaction is _________.

पर्याय

  • -k

  • k

  • `"k"/2.303`

  • `"-k"/2.303`

MCQ
रिकाम्या जागा भरा
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उत्तर

The slope of the graph ln[A]t versus t for the first-order reaction is -k.

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पाठ 6: Chemical Kinetics - Exercises [पृष्ठ १३५]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 6 Chemical Kinetics
Exercises | Q 1. v. | पृष्ठ १३५

संबंधित प्रश्‍न

Choose the most correct option.

The order of the reaction for which the units of the rate constant are mol dm-3 s-1 is _______.


Choose the most correct option.

The rate constant for the reaction \[\ce{2N2O5_{(g)} -> 2N2O4_{(g)} + O2_{(g)}}\] is `4.98 xx 10^-4 "s"^-1`. The order of reaction is _____________.


What is the half life of a first order reaction if time required to decrease concentration of reactant from 0.8 M to 0.2 M is 12 h?


Choose the most correct option.

The reaction, \[\ce{3ClO- -> ClO^-3 + 2Cl-}\] occurs in two steps, 

(i) \[\ce{2ClO- -> ClO^-2}\]

(ii) \[\ce{ClO^-2 + ClO- -> ClO^-_3 + Cl-}\] 

The reaction intermediate is _______.


Choose the most correct option.

Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.


Choose the most correct option.

For an endothermic reaction, X ⇌ Y. If Ef is the activation energy of the forward reaction and Er that for the reverse reaction, which of the following is correct?


Answer the following in one or two sentences.

For the reaction,

\[\ce{CH3Br_{(aq)} + OH^-_{ (aq)} -> CH3OH^-_{ (aq)} + Br^-_{ (aq)}}\], rate law is rate = k`["CH"_3"Br"]["OH"^-]`

What is the change in rate if concentrations of both reactants are doubled?


The rate law relates to the rate of a chemical reaction in terms of _______.


Order of reaction for which unit of rate constant is mol dm–3 s–1 is _______.


For the reaction \[\ce{2NO_{(g)} + 2H_{2(g)} -> N_{2(g)} + 2H2O_{(g)}}\],

The rate law is, rate = k[NO]2 [H2].

What is the overall order of reaction?


Write four key points about order of reaction.


Define order of reaction with suitable examples.


A reaction occurs in the following steps:

Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)

Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)

  1. Write the equation of overall reaction.
  2. Write the rate law.
  3. Identify reaction intermediate.

In a first-order reaction A → B, 60% of a given sample of a compound decomposes in 45 mins. What is the half-life of reaction? Also, write the rate law equation for the above first-order reaction.


For the non-stoichiometric reaction

\[\ce{2A + B -> C + D}\], the following kinetic data were obtained in three separate experiments, all at 298 K.

Initial concentration
(A)
Initial concentration
(B)
Initial rate of formation of C
(mol dm−3 s−1)
0.1 M 0.1 M 1.2 × 10−3
0.1 M 0.2 M 1.2 × 10−3
0.2 M 0.1 M 2.4 × 10−3

The rate law for the formation of C is:


For the reaction, \[\ce{N2(g) + 3H2(g) -> 2NH3(g); \Delta H}\] is equal to ______.


A gaseous hypothetical chemical equation \[\ce{2A ⇌ 4B + C}\] is carried out in a closed vessel. The concentration of B is found to increase by 5 × 10−3 mol dm−3 in 10 second. The rate of ____________.


The rate law for a reaction between the substances A and B is given by, rate = k[A]n [B]m. On halving the concentration of A and doubling the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as ____________.


For a hypothetical reaction \[\ce{A + B -> C}\], it is found that doubling the concentration of A increases the rate by 8 times and doubling the concentration of B increases the rate by 4 times. The overall order of the reaction is ____________.


The rate law for the reaction \[\ce{2NO_{(g)} + O2_{(g)} -> 2NO2_{(g)}}\] is rate = k[NO]2 [O2] , then which among the following statement is correct?


In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.


In the reaction \[\ce{2SO_{2_{(g)}} O_{2_{(g)}} -> 2SO_{3_{(g)}}}\], the rate of disappearance of SO2 is 1.28 × 10-5 M/s. What is the rate of appearance of SO3?


For the reaction \[\ce{2A + B -> 3C + D}\], which among the following is NOT the correct rate law expression?


Which of the following statement is not true for a reaction having rate law r = k[H2][I2]?


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