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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Observe the following and answer the question given below. Comment on the bond length of C–X bond in it.

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प्रश्न

Observe the following and answer the question given below.

Comment on the bond length of C–X bond in it.

एका वाक्यात उत्तर
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उत्तर

The bond length of C – X bond is expected to be shorter than C – X bond in haloalkanes.

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पाठ 10: Halogen Derivatives - Exercises [पृष्ठ २३३]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 10 Halogen Derivatives
Exercises | Q 7. iii. b. | पृष्ठ २३३

संबंधित प्रश्‍न

Complete the following reaction giving major products.

\[\begin{array}{cc}\ce{CH3 - CH = CH3 ->[Red P/Br2] A ->[Ag2O/H2O]B}\\|\phantom{.........................}\\
\ce{OH\phantom{.......................}}\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}\ce{CH3\phantom{................}}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3\phantom{................}}
\end{array}\]


Name the reagent used to bring about the following conversion.

Ethyl bromide to ethyl isocyanide


Arrange the following in the increasing order of boiling points.

  1. 1-Bromopropane
  2. 2- Bromopropane
  3. 1- Bromobutane
  4. 1-Bromo-2-methylpropane

Convert the following:

Propene to propan-1-ol


HCl is added to a hydrocarbon ‘A’ \[\ce{(C4H8)}\] to give a compound ‘B’ which on hydrolysis with aqueous alkali forms tertiary alcohol ‘C’ \[\ce{(C4H10O)}\]. Identify ‘A’ ,‘B’ and ‘C’.


Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.

\[\ce{Isopropyl alcohol ->[\triangle][PBr3] A ->[][NH3 excess] B}\]


Nucleophilic substitution reaction of 2, 4-dinitrochlorobenzene is faster than p-nitrochlorobenzene. Give reason.


Explain. Aryl halides are less reactive than alkyl halides towards nucleophilic substitution reactions.


Explain the factors affecting SN1 and SN2 mechanism.


What is dehydrohalogenation? State the rule for the formation of the preferred product of dehydrohalogenation.


In alkaline hydrolysis of tertiary butyl bromide, ____________.


The least reactive towards nucleophilic addition reactions is ____________.


Ethyl bromide undergoes the following reaction:

\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]

Which of the following is a WRONG statement?


Which one is most reactive towards nucleophilic addition reaction?


\[\ce{C6H5CH2Cl + KCN(alc) -> X + Y}\]

Compounds X and Y are ____________.


Identify 'B' in the following reaction.

\[\ce{2-Bromobutane ->[KOH alc.][\Delta] A ->[HI] B}\]


Convert the following.

p-Nitrochlorobenzene to p-nitrophenol


With which halogen the reactions, of alkanes are explosive?


Observe the following and answer the question given below:

Can react by SN1 mechanism? Justify your answer.


Complete the following reaction sequences by writing the structural formulae of the organic compounds 'A', 'B' and 'C'.

\[\ce{2-Bromobutan ->[alc. KOH] A ->[][Br2] B ->[][NANH2] C}\]


Define and explain the SN1 mechanism with a suitable example.


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]


Which of the following pair of compounds on heating gives butanenitrile?


Identify the substrate 'X' in the following reaction.

\[\ce{\underset{}{X + O2} ->[i) Co-naphtenate 423 K][ii) dil HClΔ] \underset{\underset{}{}}{Phenol + Acetone}}\]


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