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प्रश्न
Explain the dehydrohalogenation reaction of 2-chlorobutane.
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उत्तर
When 2-chlorobutane is boiled with an alcoholic solution of potassium hydroxide, it undergoes the elimination of the hydrogen atoms from β-carbon and chlorine atoms from α-carbon resulting in the formation of But-2-ene and But-1-ene.
Reaction:
But according to Saytzeff's rule, in dehydrohalogenation reaction, the preferred product is that alkene which has a greater number of alkyl groups attached to doubly bonded carbon atoms.
Hence, But-2-ene is obtained as the major product in the dehydrohalogenation reaction of 2-chlorobutane.
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संबंधित प्रश्न
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\[\ce{\underset{\text{(I)}}{CH3 - CH2 - CH2 - Cl}}\]
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\[\begin{array}{cc}
\ce{CH3}\\
|\\
\ce{CH3-C-Cl}\phantom{...}\\
|\\
\ce{CH3}\\
\ce{(III)}
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3}\phantom{...............}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{...............}\\
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]
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