हिंदी

The following will react faster by SN1 mechanism

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प्रश्न

The following will react faster by SN1 mechanism

विकल्प

  • 1-chloropropane

  • 2-chloropropane

  • 2-chloro-2-methylpropane

  • chloroethane

MCQ
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उत्तर

2-chloro-2-methylpropane

Explanation:

Reactivity order of alkyl halides towards SN1 mechanism: 3° > 2° > 1° > CH3X

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अध्याय 10: Halogen Derivatives - Multiple choice questions

संबंधित प्रश्न

Complete the following reaction giving major products.

\[\ce{CH3 - CH = CH2 ->[HBr][peroxide] A ->[alc. KOH] B}\]


Complete the following reaction giving major products.


Convert the following:

Benzyl alcohol to benzyl cyanide


Convert the following:

2-Chloropropane to propan-1-ol


Convert the following:

tert-Butyl bromide to isobutyl bromide


HCl is added to a hydrocarbon ‘A’ \[\ce{(C4H8)}\] to give a compound ‘B’ which on hydrolysis with aqueous alkali forms tertiary alcohol ‘C’ \[\ce{(C4H10O)}\]. Identify ‘A’ ,‘B’ and ‘C’.


Observe the following and answer the question given below.

Comment on the bond length of C–X bond in it.


Major product of the following reaction is _______________

\[\ce{CH3-CH2-Mg-Br + NH3 ->?}\]


Explain. Aryl halides are less reactive than alkyl halides towards nucleophilic substitution reactions.


In alkaline hydrolysis of tertiary butyl bromide, ____________.


Which of the following is a primary halide?


Which of the following is least reactive towards SN1 reactions?


The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:

\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]

\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]

The order of the reaction with respect to NO2(g)


Which one is most reactive towards nucleophilic addition reaction?


What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?


Which of the following carbocation is the most stable?


When C2H5Br is treated with excess of alc. NH3, the major product obtained is ____________.


Identify major product 'B' in the following reaction.

\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]


Identify 'B' in the following reaction.

\[\ce{2-Bromobutane ->[KOH alc.][\Delta] A ->[HI] B}\]


Write the product formed when alkyl halide reacts with silver nitrite.


Convert the following.

p-Nitrochlorobenzene to p-nitrophenol


The order of reactivity of the given haloalkanes towards nucleophiles is:


Complete the following reaction giving a major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Observe the following and answer the question given below:

Can react by SN1 mechanism? Justify your answer.


Complete the following reaction sequences by writing the structural formulae of the organic compounds 'A', 'B' and 'C'.

\[\ce{2-Bromobutan ->[alc. KOH] A ->[][Br2] B ->[][NANH2] C}\]


Define and explain the SN1 mechanism with a suitable example.


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]


Give a reason for the following:

Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.


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